Answer:
-1
Explanation:
The relation between Kp and Kc is given below:
Where,
Kp is the pressure equilibrium constant
Kc is the molar equilibrium constant
R is gas constant
T is the temperature in Kelvins
Δn = (No. of moles of gaseous products)-(No. of moles of gaseous reactants)
For the first equilibrium reaction:
<u>Δn = (2)-(2+1) = -1 </u>
Thus, Kp is:
Answer:
163.2g
Explanation:
First let us generate a balanced equation for the reaction. This is shown below:
4Al + 3O2 —> 2Al2O3
From the question given, were were told that 3.2moles of aluminium was exposed to 2.7moles of oxygen. Judging by this, oxygen is excess.
From the equation,
4moles of Al produced 2moles of Al2O3.
Therefore, 3.2moles of Al will produce = (3.2x2)/4 = 1.6mol of Al2O3.
Now, let us covert 1.6mol of Al2O3 to obtain the theoretical yield. This is illustrated below:
Mole of Al2O3 = 1.6mole
Molar Mass of Al2O3 = (27x2) + (16x3) = 54 + 48 =102g/mol
Mass of Al2O3 =?
Number of mole = Mass /Molar Mass
Mass = number of mole x molar Mass
Mass of Al2O3 = 1.6 x 102 = 163.2g
Therefore the theoretical of Al2O3 is 163.2g
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:
I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
Cl
=
3.5
Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
143 pm
r
C
−
F
≈
135 pm
r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
So assuming the answer is truly
C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
The now more electropositive carbon wishes to attract bonding pairs from chlorine closer, thereby shortening the
C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
<u>Answer:</u> The correct answer is Option 1.
<u>Explanation:</u>
Neutralization reaction is defined as the reaction in which acid reacts with a base to produce a salt along with water.
Here, HCl is an acid and 
is a base. When these two compounds react, the salt obtained is calcium chloride.
The equation for the above reaction is given by:
Hence, the correct answer is Option 1.
Nitrous Acid.
Hyponitrous acid: H2N2O2
Nitric acid: HNO3
Pernitric acid: HNO
