As can be seen in the attached image, α-pyrone has a highly electrophilic carbon atom, since it is attached to two oxygen atoms that are electronegative and subtract electrical charge from the carbon, leaving it with a <u>positive partial charge</u>. By virtue of the above, <u>the bromine atoms, which have an important electron density that makes them good nucleophiles, will be attracted to the aforementioned carbon due to their positive charge</u>, thus favoring the substitution product to a greater extent than that of addition.
An intensive property is a bulk property, meaning that it is a local physical property of a system that does not depend on the system size or the amount of material in the system.
MAGNESIUM(Mg) posses the up mentioned electronic configuration
Organic compounds that contain only hydrogens and carbons are known as hydrocarbons. Hydrocarbons can be saturated or unsaturated in nature. Saturated hydrocarbons are those which contain only carbon-carbon single bonds whereas unsaturated hydrocarbons contain carbon-carbon double or triple bonds. Hydrocarbons can undergo several reactions like substitution, elimination etc.
When one or more hydrogen atoms in hydrocarbon are substituted with halogen it results in the formation of haloalkane. Due to which the molecular weight increases as the halogen atoms are large compared to the carbon and hydrogen atoms. The bond becomes polar due to the presence of electronegative halogen atom and thus results in the increase in boiling point of the haloalkane.
Thus, the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.