Choose the answer that best explains why α–pyrone reacts with br2 to yield a substitution product (like benzene does), rather th
an an addition product to one of its c═c bonds.
1 answer:
As can be seen in the attached image, α-pyrone has a highly electrophilic carbon atom, since it is attached to two oxygen atoms that are electronegative and subtract electrical charge from the carbon, leaving it with a <u>positive partial charge</u>. By virtue of the above, <u>the bromine atoms, which have an important electron density that makes them good nucleophiles, will be attracted to the aforementioned carbon due to their positive charge</u>, thus favoring the substitution product to a greater extent than that of addition.
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Answer:
The new temperature of the nitrogen gas is 516.8 K or 243.8 C.
Explanation:
Gay-Lussac's law indicates that, as long as the volume of the container containing the gas is constant, as the temperature increases, the gas molecules move faster. Then the number of collisions with the walls increases, that is, the pressure increases. That is, the pressure of the gas is directly proportional to its temperature.
Gay-Lussac's law can be expressed mathematically as follows:
Where P = pressure, T = temperature, K = Constant
You want to study two different states, an initial state and a final state. You have a gas that is at a pressure P1 and at a temperature T1 at the beginning of the experiment. By varying the temperature to a new value T2, then the pressure will change to P2, and the following will be fulfilled:
In this case:
- P1= 2 atm
- T1= 50 C= 323 K (being 0 C= 273 K)
- P2= 3.2 atm
- T2= ?
Replacing:
Solving:
T2= 516.8 K= 243.8 C
<u><em>The new temperature of the nitrogen gas is 516.8 K or 243.8 C.</em></u>