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3 years ago

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Hydrogen sulfide (H2S) is a gas that smells like rotten eggs. It can be produced by bacteria in your mouth and contributes to ba

d breath. It also causes silver to tarnish so you can actually blacken silver with your breath! Let's use H2S to explore the difference in pressure exerted by an ideal versus a van der Waals gas. Calculate the pressure exerted by 1.00 mol of H2S behaving as

1 answer:

Doss [256]3 years ago

5 0

Answer:

See explanation.

Explanation:

Hello!

In this case, we consider the questions:

a. Ideal gas at:

i. 273.15 K and 22.414 L.

ii. 500 K and 100 cm³.

b. Van der Waals gas at:

i. 273.15 K and 22.414 L.

ii. 500 K and 100 cm³.

Thus, we define the ideal gas equation and the van der Waals one as shown below:

$P^{id}=\frac{nRT}{V}\\\\ P^{vdW}=\frac{RT}{v-b}-\frac{a}{v^2}$

Whereas b and a for hydrogen sulfide are 0.0434 L/mol and 4.484 L²*atm / mol² respectively, therefore, we proceed as follows:

a.

i. 273.15 K and 22.414 L.

$P^{id}=\frac{1.00mol*0.08206\frac{atm*L}{mol*K}*273.15K}{22.414L}=1 .00 atm$

ii. 500 K and 100 cm³ (0.1 L).

$P^{id}=\frac{1.00mol*0.08206\frac{atm*L}{mol*K}*500K}{0.100L}=410.3 atm$

b.

i. 273.15 K and 22.414 L: in this case, v = 22.414 L / 1.00 mol = 22.414 L/mol

$P^{vdW}=\frac{0.08206\frac{atm*L}{mol*K}*273.15K}{22.414L/mol-0.0434L/mol}-\frac{4.484 atm*L^2/mol^2}{(22.414L/mol)^2}=0.993atm$

ii. 500 K and 100 cm³: in this case, v = 0.1 L / 1.00 mol = 0.100 L/mol

$P^{vdW}=\frac{0.08206\frac{atm*L}{mol*K}*500K}{0.100L/mol-0.0434L/mol}-\frac{4.484 atm*L^2/mol^2}{(0.100L/mol)^2}=276.5atm$

Whereas we can see a significant difference when the gas is at 500 K and occupy a volume of 0.100 L.

Best regards!

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What is the [H+] if pOH =9.50 <br> will it be acid or basic?

Crank

Taking into account the definition of pH and pOH, the [H⁺] is 3.16×10⁻⁵ M and the solution will be acid.

First of all, pH is a measure of acidity or alkalinity that indicates the amount of hydrogen ions present in a solution or substance.

The pH is defined as the negative base 10 logarithm of the activity of hydrogen ions, that is, the concentration of hydrogen ions or H₃O⁺:

pH= - log [H⁺]= - log [H₃O⁺]

Similarly, pOH is a measure of hydroxyl ions in a solution and is expressed as the logarithm of the concentration of OH⁻ ions, with the sign changed:

pOH= - log [OH⁻]

The following relationship can be established between pH and pOH:

pH + pOH= 14

In this case, being pOH= 9.50, pH is calculated as:

pH + 9.40= 14

pH= 14 - 9.50

<u><em>pH= 4.50</em></u>

Replacing in the definition of pH the concentration of H⁺ ions is obtained:

- log [H⁺]= 4.50

Solving :

[H⁺]= 10⁻⁴ ⁵

<u><em>[H⁺]= 3.16×10⁻⁵ M</em></u>

The numerical scale that measures the pH of the substances includes the numbers from 0 to 14, being acidic solutions with a pH lower than 7, and basic those with a pH greater than 7. The pH = 7 indicates the neutrality of the solution.

In this case, the pH has a value of 4.50. So, the solution is acidic.

In summary, the [H⁺] is 3.16×10⁻⁵ M and the solution will be acid.

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Which one of the following is not an agent of chemical weathering?

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Explanation:

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2 years ago

The recommended maintenance dose of penicillin for children is 1.0 mg/kg/hr by injection. Of 10 mL of a 25 mg/mL solution of pen

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This problem is providing us with the recommended maintenance dose of penicillin for children as 1.0 mg/kg/hr by injection. Thus, the delivery rate for a 40-pound child is required, if 10 mL of a 25 mg/mL solution of penicillin is added to a 100-mL bottle of saline. At the end, the result is 8.0 mL/hr:

<h3>Dimensional analysis:</h3>

In chemistry, dimensional analysis allows us to obtain a specific result given relevant information about it. Although a formula is not always provided, one can use the units as a reference for the calculations.

For example, this problem asks for the rate, in mL/hr, at which a child gets this dose, so the first step will be to get the mass of the child in kilograms:

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Next, we calculate the rate at which the penicillin is delivered to this child:

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After that, we calculate the total mass of penicillin that is delivered:

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1. In the first step of the mechanism for this process, a phenoxide anion is generated. This phenoxide anion goes on to act as a

Tju [1.3M]

Answer:

See the explanation

Explanation:

In this case, in order to get an <u>elimination reaction</u> we need to have a <u>strong base</u>. In this case, the base is the phenoxide ion produced the phenol (see figure 1).

Due to the resonance, we will have a more stable anion therefore we will have a less strong base because the negative charge is moving around the molecule (see figure 2).

Finally, the phenoxide will attack the <u>primary carbon</u> attached to the Cl. The C-Cl bond would be broken and the C-O would be produced <u>at the same time</u> to get a substitution (see figure 1).

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