30 point. What is formed when a hydroxyl group is substituted for a hydrogen?

When the equation Sn + HNO₃ → SnO₂ + NO₂ + H₂O is balanced in acidic solution, what is the smallest whole-number coefficient for

balu736 [363]

Answer:

1.

Explanation:

Hello,

In this case, for the given reaction we first assign the oxidation state for each species:

$Sn^0 + H^+N^{5+}O^{-2}_3 \rightarrow Sn^{4+}O_2 + N^{4+}O^{2-}_2 + H^+_2O^-$

Whereas the half reactions are:

$Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-\\\\H^++H^+N^{5+}O^{-2}_3 +1e^-\rightarrow N^{4+}O^{2-}_2+H_2O$

Next, we exchange the transferred electrons:

$1\times(Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-)\\\\4\times (H^++H^+N^{5+}O^{-2}_3 +1e^-\rightarrow N^{4+}O^{2-}_2+H_2O)\\\\\\Sn^0+2H_2O \rightarrow Sn^{4+}O_2 +4H^++4e^-\\\\4H^++4H^+N^{5+}O^{-2}_3 +4e^-\rightarrow 4N^{4+}O^{2-}_2+4H_2O$

Afterwards, we add them to obtain:

$Sn^0+2H_2O+4H^++4H^+N^{5+}O^{-2}_3 \rightarrow Sn^{4+}O_2 +4H^++4N^{4+}O^{2-}_2+4H_2O$

By adding and subtracting common terms we obtain:

$Sn^0+4H^+N^{5+}O^{-2}_3 \rightarrow Sn^{4+}O_2 +4N^{4+}O^{2-}_2+2H_2O$

Finally, by removing the oxidation states we have:

$Sn + 4HNO_3 \rightarrow SnO_2 + 4NO_2 + 2H_2O$

Therefore, the smallest whole-number coefficient for Sn is 1.

Regards.

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Read 2 more answers

You need to prepare 1 L of the citric acid/citrate buffer. You have chosen to use Method 1 (see lab presentation). Calculate the

prisoha [69]

Answer:

3.11 is the pH of the buffer

Explanation:

The pH of a buffer is obtained using H-H equation:

pH = pKa + log [Conjugate base] / [Weak acid]

Where pH is the pH of the buffer, pKa = -log Ka = 3.14 for the citric buffer and [] could be taken as the moles of each species.

The citric acid,HX (Weak acid), reacts with NaOH to produce sodium citrate, NaX (weak base) and water:

HX + NaOH → H2O + NaX

That means the moles of NaOH added = Moles of sodium citrate produced

And the resulitng moles of HX = Initial moles - Moles NaOH added

Moles HX and NaX:

Moles NaOH = 0.100L * (0.65mol / L) = 0.065 moles NaOH = Moles NaX

Moles HX = 0.300L * (0.45mol / L) = 0.135 moles HX - 0.065 moles NaOH = 0.070 moles HX

Replacing in H-H equation:

pH = 3.14 + log [0.065mol] / [0.070mol]

pH = 3.11 is the pH of the buffer

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