The reaction between the reactants would be:
CH₃NH₂ + HCl ↔ CH₃NH₃⁺ + Cl⁻
Let the conjugate acid undergo hydrolysis. Then, apply the ICE approach.
CH₃NH₃⁺ + H₂O → H₃O⁺ + CH₃NH₂
I 0.11 0 0
C -x +x +x
E 0.11 - x x x
Ka = [H₃O⁺][CH₃NH₂]/[CH₃NH₃⁺]
Since the given information is Kb, let's find Ka in terms of Kb.
Ka = Kw/Kb, where Kw = 10⁻¹⁴
So,
Ka = 10⁻¹⁴/5×10⁻⁴ = 2×10⁻¹¹ = [H₃O⁺][CH₃NH₂]/[CH₃NH₃⁺]
2×10⁻¹¹ = [x][x]/[0.11-x]
Solving for x,
x = 1.483×10⁻⁶ = [H₃O⁺]
Since pH = -log[H₃O⁺],
pH = -log(1.483×10⁻⁶)
<em>pH = 5.83</em>
The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴ ![8.3 = 8.3 + log \frac{[0.005]}{[0.005]}](https://tex.z-dn.net/?f=8.3%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005%5D%7D%7B%5B0.005%5D%7D)
<em> </em>inverse log 0 = ![\frac{[B]}{[A]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D)
![\frac{[B]}{[A]} = 1](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D%20%3D%201)
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
![pH = 8.3 + log \frac{[0.005-0.003]}{[0.005+0.003]}\\pH = 8.3 + log \frac{[0.002]}{[0.008]}\\\\pH = 8.3 + log {0.25}\\\\pH = 8.3 + (-0.62)\\pH = 7.69](https://tex.z-dn.net/?f=pH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005-0.003%5D%7D%7B%5B0.005%2B0.003%5D%7D%5C%5CpH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.002%5D%7D%7B%5B0.008%5D%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20log%20%7B0.25%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20%28-0.62%29%5C%5CpH%20%3D%207.69)
Therefore, the new pH is 7.69.
Learn more about pH here:
brainly.com/question/24595796
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In order to make the dissolution of the solid compound in water to occur at a faster rate, Samuel could do the following:
1. Break down the solid into tiny particles: breaking down the solid into tiny particles increases the surface area of the solid and thus increase the quantity of the substance that comes in contact with the solvent per time, this leads to a faster dissolution of the solid.
2. Stir the liquid with iron rod: Samuel can increase the dissolution rate of the substance by stirring it continuously with iron rod.
3. Increasing the temperature:Samuel could also increase the rate of dissolution of the substance by increasing the temperature of the water.
