Thermochemistry

A compound contains 6.0 g of carbon and 1.0 g of hydrogen and has a molar mass of 42.0 g/mol.

makvit [3.9K]

Answer:

%C = 85.71 wt%; %H = 14.29 wt%; Empirical Formula => CH₂; Molecular Formula => C₃H₆

Explanation:

%Composition

Wt C = 6 g

Wt H = 1 g

TTL Wt = 6g + 1g = 7g

%C per 100wt = (6/7)100% = 85.71 wt%

%H per 100wt = (1/7)100% = 14.29 wt % or, %H = 100% - %C = 100% - 85.71% = 14.29 wt% H

What you should know when working empirical formula and molecular formula problems.

Empirical Formula=> <u>smallest</u> whole number ratio of elements in a compound

Molecular Formula => <u>actual</u> whole number ratio of elements in a compound

Empirical Formula Weight x Whole Number Multiple = Molecular Weight

From elemental %composition values given (or, determined as above), the empirical formula type problem follows a very repeatable pattern. This is ...

% => grams => moles => ratio => reduce ratio => empirical ratio

for determination of molecular formula one uses the empirical weight - molecular weight relationship above to determine the whole number multiple for the molecular ratios.

Caution => In some 'textbook' empirical formula problems, the empirical ratio may contain a fraction in the amount of 0.25, 0.50 or 0.75. If such an issue arises, multiply all empirical ratio numbers containing 0.25 and/or 0.75 by '4' to get the empirical ratio and multiply all empirical ration numbers containing 0.50 by '2' to get the final empirical ratio.

This problem:

Empirical Formula:

Using the % per 100wt values in part 'a' ...

% => grams => moles

%C => 85.71% => 85.71 g* / 100 g Cpd => (85.71 / 12) = 7.14 mol C

%H => 14.29% => 14.29 g / 100 g Cpd => (14.29 / 1) = 14.29 mol H

=> Set up mole Ratio and Reduce to Empirical Ratio:

mole ratio C:H => 7.14 : 14.29

<u>To reduce mole values to the smallest whole number ratio, divide all mole values by the smaller mole value of the set.</u>

=> 7.14/7.14 : 14.29/7.14 => Empirical Ration=> 1 : 2

∴ Empirical Formula => CH₂

Molecular Formula:

(Empirical Formula Wt)·N = Molecular Wt => N = Molecular Wt / Empirical Wt

N = 42 / 14 = 3 => multiply subscripts of empirical formula by '3'.

Therefore, the molecular formula is C₃H₆

3 0

3 years ago

An ideal gas contained in a piston-cylinder assembly is compressed isothermally in an internally reversible process.

Tju [1.3M]

Answer:

a) $\Delta S$

b) entropy of the sistem equal to a), entropy of the universe grater than a).

Explanation:

a) The change of entropy for a reversible process:

$\delta S=\frac{\delta Q}{T}$

$\Delta S=\frac{Q}{T}$

The energy balance:

$\delta U=[tex]\delta Q- \delta W$

If the process is isothermical the U doesn't change:

$0=[tex]\delta Q- \delta W$

$\delta Q= \delta W$

$Q= W$

The work:

$W=\int_{V1}^{V2}P*dV$

If it is an ideal gas:

$P=\frac{n*R*T}{V}$

$W=\int_{V1}^{V2}\frac{n*R*T}{V}*dV$

Solving:

$W=n*R*T*ln(V2/V1)$

Replacing:

$\Delta S=\frac{n*R*T*ln(V2/V1)}{T}$

$\Delta S=n*R*ln(V2/V1)}$

Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:

$\Delta S$

b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.

7 0

4 years ago

1.5 moles of Al is how many<br> atoms?

aev [14]

Answer:

<h2>9.03 × 10²³ atoms </h2>

Explanation:

The number of atoms of Al can be found by using the formula

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

N = 1.5 × 6.02 × 10²³

We have the final answer as

<h3>9.03 × 10²³ atoms</h3>

Hope this helps you

4 0

3 years ago

Which is the correct Lewis dot structure of NH2?<br><br> A.A<br> B.B<br> C.C<br> D.D<br> E.E

Anarel [89]

I think D is your answer

5 0

3 years ago

Read 2 more answers

All p block elements form ions.<br> True or False

FinnZ [79.3K]

Answer:

No this statement is false.

Explanation:

when an atom lose or gain the electron ions are formed. If the atom lose an electron the positive ions are formed called cations while anion is formed by the gaining of electron by an atom The elements having less electrons in valance shell usually lose their electrons while the elements like halogens having 7 valance electrons gain an electron to complete the octet. while p block elements noble gases are inert, their outer most valance shell is complete so they do not form ions.

P block elements are non-metals, metals and metalloids. These are thirty five elements. The P-block elements are present on right side of periodic table. There valance electrons are present in P orbital. The p-block metals are shiny and good conductor of heat and electricity. These metal lose the electron which is accept by non metals and form ionic bond. They have high melting points.

Metalloids includes boron, silicon, germanium, arsenic, antimony and tellurium. Metalloids contain both the properties of metals and non metals, Some metalloids are toxic like arsenic.

Most of p-block elements are non metals. They are bad conductor of heat and electricity and have low boiling points. The non metals mostly accept the electron from the metals and usually from ionic bond like in case of chlorine. It form the ionic compound with sodium.

The sodium chloride which is an ionic compound, formed by the complete transfer of electron from sodium to chlorine atom and form ionic bond. In this ionic compound sodium carry positive charge and chlorine carry negative charge there is attraction between these oppositely charged atoms.

4 0

4 years ago