Answer : Option 1) nuclei of
and nuclei of
only.
Explanation : Radiation is spontaneously emitted from nuclei of
because this isotope of hydrogen is highly radioactive as compared to other isotopes of hydrogen namely; nuclei of
and nuclei of
.
They have much stable nucleus as compared to nuclei of
.
The more it is unstable the more radiations will be emitted from its nucleus.
<u>Answer:</u> The rate law of the reaction is ![\text{Rate}=k[HgCl_2][C_2O_4^{2-}]^2](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5BC_2O_4%5E%7B2-%7D%5D%5E2)
<u>Explanation:</u>
Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
For the given chemical equation:

Rate law expression for the reaction:
![\text{Rate}=k[HgCl_2]^a[C_2O_4^{2-}]^b](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5Ea%5BC_2O_4%5E%7B2-%7D%5D%5Eb)
where,
a = order with respect to 
b = order with respect to 
Expression for rate law for first observation:
....(1)
Expression for rate law for second observation:
....(2)
Expression for rate law for third observation:
....(3)
Expression for rate law for fourth observation:
....(4)
Dividing 2 from 1, we get:

Dividing 2 from 3, we get:

Thus, the rate law becomes:
![\text{Rate}=k[HgCl_2]^1[C_2O_4^{2-}]^2](https://tex.z-dn.net/?f=%5Ctext%7BRate%7D%3Dk%5BHgCl_2%5D%5E1%5BC_2O_4%5E%7B2-%7D%5D%5E2)