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Thepotemich [5.8K]
3 years ago
13

Give the structure that corresponds to the following molecular formula and 1H NMR spectrum: C4H10O2: δ 1.36 (3H, d, J = 5.5 Hz);

δ 3.32 (6H, s); δ 4.63 (1H, q, J = 5.5 Hz)can you explain how to get the answer how do you use the shift, d,s,q to figure out the problem and the importance of J
Chemistry
1 answer:
kondor19780726 [428]3 years ago
6 0

Answer:

For the determination of a structure through its NMR it is necessary to know its molecular formula as well as the delta values, its coupling and the shift of each signal.

The separation produced is called coupling constant J and is measured in Hz. If the split is produced by two equal protons (equal J) a triple signal known as triplet is produced and if produced by three equal protons, the signal is quadruple and is known as quadruplet. The magnitude of the coupling is varied, depending on the relative disposition of the coupled protons (elevations that separate them, arrangement, spatial arrangement)

OH CH2 CH2 CH2 CH2 OH

(A)   (B)   (C)

1,4-butanediol

In the case of the molecule to study the signal at 1.36 shows a doublet, which corresponds to the hydrogen (C), is split in two for each different proton on the same carbon or on neighboring carbons.

At 3.32 ocurrs a singlet, wich belong to hidrogen (B). The last signal is a quintet, at 4.63 belonging to the hydrogen (C)

Explanation

Nuclear magnetic resonance NMR is a physical phenomenon based on the mechanical-quantum properties of atomic nuclei. NMR also refers to the family of scientific methods that explore this phenomenon to study molecules, macromolecules, as well as tissues and whole organisms.

NMR takes advantage of the fact that atomic nuclei resonate at a frequency directly proportional to the force of a magnetic field exerted, in accordance with the Larmor precession frequency equation, to subsequently disturb this alignment with the use of an alternating magnetic field, of orthogonal orientation.

The behavior of the nuclei in the magnetic field can be influenced in multiple ways, to give different types of information, but the basic information obtained is:

  • Frequency at which each particular nuclei comes out, displacement.
  • Number of nucleis of each type, integral.
  • Number and arrangement of nearby nuclei, multiplicity.
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What physical change happens to atoms and molecules in a solution that is strongly heated in a flame? Is there a phase change? I
Charra [1.4K]

When atoms and molecules speed up or slow down, that is a physical change. When they change state from liquid to solid or from gas to liquid, that is a physical change. ... The ions or molecules can still come back together to form the original substance

6 0
2 years ago
David walks 10 Km North. He turns East and walks 10 more Km. What is his distance
BigorU [14]

Answer:

20 km

Explanation:

he walks 10 km + another 10 km so 20 :)

3 0
3 years ago
To measure the speed of a car, we use miles per hour (miles/hour or mi/h or mph). To measure the rate of a reaction we use molar
arsen [322]

Answer:

Part A: 47.8 mi/h

Part B: 0.072 M/s

Part C: 0.144 M/s

Explanation:

Part A

The average speed or velocity (V) is the variation of the space divided by the variation of the time:

V = (241 - 2)/(8 -3)

V = 47.8 mi/h

Part B

As Part A, the average rate (r) of formation of I2 is the variation of the concentration divided by the variation of time:

r = (1.83 - 1.11)/(15 - 5)

r = 0.072 M/s

Part C

The rates of the substances are proportional of their number of moles (n) which are their coefficient, so:

rI2/nI2 = rHCl/nHCl

0.072/1 = rHCl/2

rHCl = 2*0.072

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7 0
3 years ago
Calculate the molecular weight of chalk.write any two advantages of mandeleev's periodic table?
Debora [2.8K]
Part (a):
Chalk has the chemical formula: CaCo₃
From the periodic table:
mass of Ca = 40 grams
mass of Co = 58.9 grams
Therefore:
molecular weight of chalk = 40 + 3(58.9) = 216.7 grams

Part (b):
Advantages of M<span>andeleev's periodic table:
1- Could predict the properties of elements easily based on its position in the periodic table
2- Elements were arranged systematically in order of increasing atomic mass which helped in the study and classification of elements
3- Even after the discovery of noble gases, no major changes needed to be done to the periodic table. Noble gases were inserted easily
4- He left room for other undiscovered elements based on his systematic approach in writing the table

Hope this helps :)</span>
5 0
3 years ago
SHOW ALL WORK AND INCLUDE UNITS
Oksana_A [137]

Answer:

0.72 mole of oxygen would produce 320.4 kJ of heat.

Explanation:

CH₄ (g) + 2O₂ (g) → CO₂ (g) + 2H₂O (ℓ) + 890kJ

According to the equation,

2 moles of O₂ produces 890 kJ of heat

So, 0.72 moles of O₂ will produce:

Therefore, 0.72 moles of oxygen would produce 320.4 kJ of heat.

4 0
3 years ago
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