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The equilibrium constant Kc for the reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) is 49 at 230°C. If 0.70 mol of PCl3 is added to 0.70 mol

Ymorist [56]

Answer : The correct option is, (B) 0.11 M

Solution :

First we have to calculate the concentration $PCl_3$ and $Cl_2$ .

$\text{Concentration of }PCl_3=\frac{\text{Moles of }PCl_3}{\text{Volume of solution}}$

$\text{Concentration of }PCl_3=\frac{0.70moles}{1.0L}=0.70M$

$\text{Concentration of }Cl_2=\frac{\text{Moles of }Cl_2}{\text{Volume of solution}}$

$\text{Concentration of }Cl_2=\frac{0.70moles}{1.0L}=0.70M$

The given equilibrium reaction is,

$PCl_3(g)+Cl_2(g)\rightleftharpoons PCl_5(g)$

Initially 0.70 0.70 0

At equilibrium (0.70-x) (0.70-x) x

The expression of $K_c$ will be,

$K_c=\frac{[PCl_5]}{[PCl_3][Cl_2]}$

$K_c=\frac{(x)}{(0.70-x)\times (0.70-x)}$

Now put all the given values in the above expression, we get:

$49=\frac{(x)}{(0.70-x)\times (0.70-x)}$

By solving the term x, we get

$x=0.59\text{ and }0.83$

From the values of 'x' we conclude that, x = 0.83 can not more than initial concentration. So, the value of 'x' which is equal to 0.83 is not consider.

Thus, the concentration of $PCl_3$ at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M

The concentration of $Cl_2$ at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M

The concentration of $PCl_5$ at equilibrium = x = 0.59 M

Therefore, the concentration of $PCl_3$ at equilibrium is 0.11 M

3 0

3 years ago

Jim drops an iron magnet during a chemistry lab experiment. He finds that it is no longer magnetic. What has happened in terms o

jok3333 [9.3K]

Answer: option A.

A physical change occurred in which the iron remained iron, but lost one of its physical properties

Explanation: magnetization and demagnetization is a physical change as no new substance is form and it is easily reversed. When an iron rod is magnetized, it can loss it magnetic property by hitting it. So when an iron rod which is magnetized falls from a height it can also loss its magnetic property

4 0

3 years ago

Read 2 more answers

A horizontal row of elements in the periodic table represents a<br> group<br> period

castortr0y [4]

Answer:

Period

Explanation:

Periodic trend along period:

As we move from left to right across the periodic table the number of valance electrons in an atom increase. The atomic size tend to decrease in same period of periodic table because the electrons are added with in the same shell. When the electron are added, at the same time protons are also added in the nucleus. The positive charge is going to increase and this charge is greater in effect than the charge of electrons. This effect lead to the greater nuclear attraction.

The electrons are pull towards the nucleus and valance shell get closer to the nucleus. As a result of this greater nuclear attraction atomic radius decreases and ionization energy increases because it is very difficult to remove the electron from atom and more energy is required.The electron affinity also increases along period because of greater positive charge.

7 0

2 years ago

Is it possible to make crystals by hand?

xeze [42]

Answer: Crystals are formed by the earth and the earth itself otherwise then its a fake crystal

Explanation:

Every crystal that exists was formed when earth was formed. Take diamonds for example, All diamonds were crushed for millions of years by the earth and that's why they are so valuable. All diamonds are just coal.

So your answer is no but fake crystals yes

8 0

2 years ago

Nitrogen gas has a density of 4.566 g/L and liquid nitrogen density is 809.0 g/L.

DedPeter [7]

Answer:

OOFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF

Explanation:

IM in 7th dont ask me bro

6 0

2 years ago