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madreJ [45]
3 years ago
13

How much work (in JJ) is required to expand the volume of a pump from 0.0 LL to 2.5 LL against an external pressure of 1.1 atmat

m
Chemistry
1 answer:
stira [4]3 years ago
8 0

Answer:

- 278.85 J  

Explanation:

Given that:

Pressure = 1.1 atm

The initial volume V₁ = 0.0 L

The final volume V₂ = 2.5 L

The work that takes place in a reaction at constant pressure can be expressed by using the equation:

W = P(V₂ - V₁ )

Since the volume of the gas is expanded from 0 to 2.5 L when 1.1 atm pressure is applied. Then, the work can be given by the expression:

W = - P(V₂ - V₁ )

W = -1.1 atm ( 2.5 - 0.0) L

W = -1.1 atm (2.5 L)

W = -2.75 atm L

Recall that:

1 atm L = 101.4 J

Therefore;

-2.75 atm L = ( -2.75 × 101.4 )J

= -278.85 J  

Thus, the work required at the chemical reaction when the pressure applied is 1.1 atm  = - 278.85 J  

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Hydrogen gas (a potential future fuel) can be formed by the reaction of methane with water according to the following equation:
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60.42% is the percent yield of the reaction.

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Temperature of the methane gas = T = 25 °C = 298.15 K

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Pressure of water vapor = P' = 700 Torr = 0.9100 atm

Temperature of  water vapor = T' = 125 °C = 398.15 K

Moles of water vapor gas = n'

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CH_4(g)+H_2O(g)\rightarrow CO(g)+3H_2(g)

According to reaction , 1 mol of methane reacts with 1 mol of water vapor. As we can see that moles of water vapors are in lessor amount which means it is a limiting reagent and formation of hydrogen gas will depend upon moles of water vapors.

According to reaction 1 mol of water vapor gives 3 moles of hydrogen gas.

Then 0.6402 moles of water vapor will give:

\frac{3}{1}\times 0.6402 mol=1.9208 mol of hydrogen gas

Moles of hydrogen gas obtained theoretically = 1.9208 mol

The reaction produces 26.0 L of hydrogen gas measured at STP.

At STP, 1 mole of gas occupies 22.4 L of volume.

Then 26 L of volume of gas will be occupied by:

\frac{1}{22.4 L}\times 26 L= 1.1607 mol

Moles of hydrogen gas obtained experimentally = 1.1607 mol

Percentage yield of hydrogen gas of the reaction:

\frac{Experimental}{Theoretical}\times 100

\%=\frac{ 1.1607 mol}{1.9208 mol}\times 100=60.42\%

60.42% is the percent yield of the reaction.

8 0
3 years ago
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