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dusya [7]
3 years ago
13

Please answer

Chemistry
1 answer:
Oksana_A [137]3 years ago
3 0

Answer:

Q = -15363.65 J

Explanation:

Given data:

Number of moles of water = 2.0 mol

Initial temperature = 101°C

Final temperature = -1.0°C

Total energy lost = ?

Solution:

Mass of water:

Mass = number of moles × molar mass

Mass = 2 mol × 18 g/mol

Mass = 36 g

Heat lost:

specific heat capacity of water is 4.184 J/g.°C

Formula:

Q = m.c. ΔT

Q = amount of heat absorbed or released

m = mass of given substance

c = specific heat capacity of substance

ΔT = change in temperature

ΔT =  -1.0°C -  101°C

ΔT =  -102°C

Q = 36 g × 4.184 J/g.°C × -102°C

Q = -15363.65 J

Negative sign show heat is released.

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For the reaction A + B + C → D + E, the initial reaction rate was measured for various initial concentrations of reactants. The
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Answer : The rate for trial 5 will be 4.25\times 10^{-2}Ms^{-1}

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

A+B+C\rightarrow D+E

Rate law expression for the reaction:

\text{Rate}=k[A]^a[B]^b[C]^c

where,

a = order with respect to A

b = order with respect to B

c = order with respect to C

Expression for rate law for first observation:

6.0\times 10^{-4}=k(0.20)^a(0.20)^b(0.20)^c ....(1)

Expression for rate law for second observation:

1.8\times 10^{-3}=k(0.20)^a(0.20)^b(0.60)^c ....(2)

Expression for rate law for third observation:

2.4\times 10^{-3}=k(0.40)^a(0.20)^b(0.20)^c ....(3)

Expression for rate law for fourth observation:

2.4\times 10^{-3}=k(0.40)^a(0.40)^b(0.20)^c ....(4)

Dividing 1 from 2, we get:

\frac{1.8\times 10^{-3}}{6.0\times 10^{-4}}=\frac{k(0.20)^a(0.20)^b(0.60)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\3=3^c\\c=1

Dividing 1 from 3, we get:

\frac{2.4\times 10^{-3}}{6.0\times 10^{-4}}=\frac{k(0.40)^a(0.20)^b(0.20)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\4=2^a\\a=2

Dividing 3 from 4, we get:

\frac{2.4\times 10^{-3}}{2.4\times 10^{-3}}=\frac{k(0.40)^a(0.40)^b(0.20)^c}{k(0.40)^a(0.20)^b(0.20)^c}\\\\1=2^b\\b=0

Thus, the rate law becomes:

\text{Rate}=k[A]^2[B]^0[C]^1

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

6.0\times 10^{-4}=k(0.20)^2(0.20)^0(0.20)^1

k=7.5\times 10^{-2}M^{-2}s^{-1}

Thus, the value of the rate constant 'k' for this reaction is 7.5\times 10^{-2}M^{-2}s^{-1}

Now we have to calculate the rate for trial 5 that starts with 0.90 M of reagent A, 0.60 M of reagents B and 0.70 M of reagent C.

\text{Rate}=k[A]^2[B]^0[C]^1

\text{Rate}=(7.5\times 10^{-2})\times (0.90)^2(0.60)^0(0.70)^1

\text{Rate}=4.25\times 10^{-2}Ms^{-1}

Therefore, the rate for trial 5 will be 4.25\times 10^{-2}Ms^{-1}

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