Burning wood represents a chemical change. True or False?

There are ________ σ bonds and ________ π bonds in h3c-ch2-ch=ch-ch2-c≡ch.

FrozenT [24]

The number of sigma and pi bonds are,

Sigma Bonds = 16

Pi Bonds = 3

Explanation:
Every first bond formed between two atoms is sigma. Pi bond is formed when already a sigma bond is there. While in case of Alkyne (triple Bond) there is one sigma and one pi bond already present, so the third bond is formed by second side-to-side overlap of orbitals, hence, a second pi bond is formed.
Below all black bonds are sigma bonds, while in alkene there is one pi bond and in alkyne there are two pi bonds.

6 0

3 years ago

Potassium nitrate has a lattice energy of -163.8 kcal/mol and a heat of hydration of -155.5 kcal/mol.

Brut [27]

Answer:

293.99 g

OR

0.293 Kg

Explanation:

Given data:

Lattice energy of Potassium nitrate (KNO3) = -163.8 kcal/mol

Heat of hydration of KNO3 = -155.5 kcal/mol

Heat to absorb by KNO3 = 101kJ

To find:

Mass of KNO3 to dissolve in water = ?

Solution:

Heat of solution = Hydration energy - Lattice energy

= -155.5 -(-163.8)

= 8.3 kcal/mol

We already know,

1 kcal/mol = 4.184 kJ/mole

Therefore,

= 4.184 kJ/mol x 8.3 kcal/mol

= 34.73 kJ/mol

Now, 34.73 kJ of heat is absorbed when 1 mole of KNO3 is dissolved in water.

For 101 kJ of heat would be

= 101/34.73

= 2.908 moles of KNO3

Molar mass of KNO3 = 101.1 g/mole

Mass of KNO3 = Molar mass x moles

= 101.1 g/mole x 2.908

= 293.99 g

= 0.293 kg

293.99 g potassium nitrate has to dissolve in water to absorb 101 kJ of heat.

4 0

3 years ago

Identify the basic structure of a chemical equation?

antiseptic1488 [7]

It is the crust, the least dense layer.

3 0

3 years ago

I need help with this assignment

yuradex [85]

The answers for the following sums is given below.

1. $Pd_{2}H_{2}$

2. $C_{2} H_{6}$

3. $C_{2} H_{2} O_{2} Cl_{2}$

4. $C_{3}Cl_{3} N_{3}$

5. $Tl_{2 } C_{4} H_{4}O_{6}$

6. $C_{8}H_{8}$

7. $N_{2}O_{5}$

8. $P_{4}O_{6}$

9. $C_{4}H_{8} O_{2}$

Explanation:

1.Given:

Molar mass=216.8g

Molecular formula=Pd $H_{2}$

we know;

Molecular formula=n(Empirical formula)

molecular weight of palladium(Pd)=106.4u

molecular weight of hydrogen(H)=1u

Molar mass of Pd $H_{2}$ :

Pd=106.4×1=106.4u

H=1×2=2

molar mass of Pd $H_{2}$ =106.4+2=108.4

n= $\frac{216.8}{106.4}$

n=2

Molecular formula=2(Pd $H_{2}$ )

Molecular formula= $Pd_{2}H_{2}$

Therefore the molecular formula of the compound is $Pd_{2}H_{2}$

2. Given:

Molar mass=30.0g

Molecular formula= $CH_{3}$

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of hydrogen(H)=1u

Molar mass of $CH_{3}$ :

C=12.01 × 1 = 12.01u

H=1 × 3 = 3u

molar mass of $CH_{3}$ =12.01 + 3 =15.01u

n= $\frac{30.0}{15.01}$

n=2

Molecular formula=2( $CH_{3}$ )

Molecular formula= $C_{2} H_{6}$

Therefore the molecular formula of the compound is $C_{2} H_{6}$

3. Given:

Molar mass=129g

Molecular formula=CHOCl

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of hydrogen(H)=1u

molecular weight of oxygen(O)=16.00u

molecular weight of chlorie(Cl)=35.5u

Molar mass of CHOCl:

C=12.01 × 1 = 12.01u

H=1 × 1 = 1u

O=16.00×1=16.00u

Cl=35.5×1=35.5u

molar mass of CHOCl=12.01+1+16.00+35.5=64.5u

n= $\frac{129}{64.5}$

n=2

Molecular formula=2(CHOCl)

Molecular formula= $C_{2} H_{2} O_{2} Cl_{2}$

Therefore the molecular formula of the compound is $C_{2} H_{2} O_{2} Cl_{2}$

5. Given:

Molar mass=577g

Molecular formula= $TlC_{2} H_{2}O_{3}$

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of Thallium(Tl)=204.3u

molecular weight of hydrogen(H)=1u

molecular weight of oxygen(O)=16.00u

Molar mass of $TlC_{2} H_{2}O_{3}$ :

C=12.01 × 2= 24.02u

Tl=204.3×1=204.3u

H=1×2=2u

O=16.00×3=48.00

molar mass of $TlC_{2} H_{2}O_{3}$ =204.3+24.02+1+48.00=278.32u

n= $\frac{577}{278.32}$

n=2

Molecular formula=2 ( $TlC_{2} H_{2}O_{3}$ )

Molecular formula= $Tl_{2 } C_{4} H_{4}O_{6}$

Therefore the molecular formula of the compound is $Tl_{2 } C_{4} H_{4}O_{6}$

4. Molar mass=184.5g

Molecular formula=CClN

we know;

Molecular formula = n (Empirical formula)

molecular weight of Carbon(C)=12.01u

molecular weight of Nitrogen(N)=14u

molecular weight of chlorine(Cl)=35.5u

Molar mass of CClN:

C=12.01 × 1 = 12.01u

N=1×14=14U

Cl=35.5×1=35.5u

molar mass of CClN=12.01+14+35.5=61.5u

n= $\frac{184.5}{61.5}$

n=3

Molecular formula=3 (CClN)

Molecular formula= $C_{3}Cl_{3} N_{3}$

Therefore the molecular formula of the compound is $C_{3}Cl_{3} N_{3}$

6. For the table refer the attached file.

Simplest ratio of elements:

Carbon=8

Hydrogen=8

Empirical formula= $C_{8}H_{8}$

Molecular formula = $C_{8}H_{8}$

Molar mass of $C_{8}H_{8}$ :

molecular weight of carbon=12.04u

molecular weight of hydrogen=1u

C=8×12.01=96.08u

H=1×8=8u

molar mass of $C_{8}H_{8}$ =96.08+8=104.08u

n=104.08÷78.0

n=1

Molecular formula = n(Empirical formula)

Molecular formula = 1( $C_{8}H_{8}$ )

Molecular formula = $C_{8}H_{8}$

Therefore the molecular formula of a compound is $C_{8}H_{8}$

7. Given:

mass of oxide of nitrogen=108g

mass of nitrogen=4.02g

mass of oxygen=11.48g

moles of nitrogen= $\frac{4.04}{14.01}$ = 0.289 moles

moles of oxygen= $\frac{11.46}{15.999}$ =0.716 moles

We divide through by the lowest molar quantity to give an empirical formula of $N_{2} O{5}$ .

Now the molecular formula is multiple of the empirical formula.

So,

108 = n × (2×14.01 + 5×15.999)

Clearly,n=1, and the molecular formula is $N_{2}O_{5}$ .

8.For the table refer the attached file.

Simplest ratio of elements:

Phosphorus=2

Oxygen=3

We know;

Empirical formula= $P_{2} O_{3}$

molecular formula= 2(Empirical formula)

Molecular formula =2( $P_{2} O_{3}$ )

Molecular formula = $P_{4}O_{6}$

Therefore the molecular formula of the compound is $P_{4}O_{6}$

9. For the table refer the attached file.

Simplest ratio of elements:

Carbon=2

Hydrogen=9

Oxygen=2

We know;

Empirical formula = $C_{2} H_{4} O$

Molecular formula = 2(Empirical formula)

Molecular formula =2( $C_{2} H_{4} O$ )

Molecular formula = $C_{4}H_{8} O_{2}$

Therefore the molecular formula of the compound is $C_{4}H_{8} O_{2}$

4 0

3 years ago

Jason measures three values of density for his unknown. The values he obtains are: 1.019 g/mL 1.498 g/mL 1.572 g/mL What is the

jok3333 [9.3K]

Answer: The average of the densities of the given measurements is 1.363 g/mL

Explanation:

The equation used to calculate density of a substance is given by:

$\text{Density of a substance}=\frac{\text{Mass of a substance}}{\text{Volume of a substance}}$

We are given:

First measured value of density, $d_1$ = 1.019 g/mL

Second measured value of density, $d_2$ = 1.498 g/mL

Third measured value of density, $d_3$ = 1.572 g/mL

Putting values in above equation, we get:

$\rho_{mix}=\frac{d_1+d_2+d_3}{3}$

$\rho=\frac{1.019+1.498+1.572}{3}\\\\\rho=1.363g/mL$

Hence, the average of the densities of the given measurements is 1.363 g/mL

7 0

3 years ago