Explain the regiochemical outcome for chlorination of bromobenzene.
1 answer:
Answer:
See explanation
Explanation:
In a chemical reaction, a particular reaction path may be favoured due to the fact that it is energetically more favourable(lower energy sigma complex is formed).
The more the resonance structures produced in a particular reaction pathway, the more energetically favourable it is.
In the chlorination of bromobenzene, ortho attack and para attack are preferred because each of these pathways involves a sigma complex with__4________resonance structures. Attack at the meta position involves formation of a sigma complex with only____3_______ resonance structures. The reaction will proceed more rapidly via the_____lower_______ energy sigma complex, so attack takes place at the ortho and para positions in preference to the meta position.
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PH = pKa + log ![\frac{[base]}{[Acid]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5Bbase%5D%7D%7B%5BAcid%5D%7D%20)
Acid is HC₂H₃O₂ and conjugate base is KC₂H₃O₂,
pKa = - log Ka = - log (1.8 x 10⁻⁵) = 4.74
so pH = 4.74 + log (0.2/0.2) = 4.74
This is called maximum buffer capacity (when acid conc. and base conc. are equal) the pH = pKa in this case
Acid is HC₂H₃O₂ and conjugate base is KC₂H₃O₂,
pKa = - log Ka = - log (1.8 x 10⁻⁵) = 4.74
so pH = 4.74 + log (0.2/0.2) = 4.74
This is called maximum buffer capacity (when acid conc. and base conc. are equal) the pH = pKa in this case