prove that the heat transfer at the constant pressure is given by the enthalpy change during the process
1 answer:
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Answer:
Explanation:
There are a total of 6 states and 3 bits in this problem. Whenever the Reset button is pressed, RESET state is called otherwise the state according to the diagram is called. For the combination to be "01011", the input sequence has to be in the same order. If 0 is pressed instead of 1 in state "010", the last state of output ending with 0 will be called and likewise in all the states that follow.
Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation
And
a=
b=
Now calculate V1 and V2 at given condition
Substitute given values = 1 x 10^5 , T = 373.15 and given values of coefficients we get
Solve for V1 by iterative or alternative cubic equation solver we get
Similarly solve for state 2 at P2 = 50 bar we get
Now
a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is
a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series