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Sav [38]
3 years ago
14

In class we derived the Gibbs energy of mixing for a binary mixture of perfect gases. We also discussed that the same result is

obtained for liquids when the resulting solution is ideal. For real solutions we introduced activities and activity coefficients. Derive the molar Gibbs energy of mixing and the molar excess Gibbs energy of mixing in terms of activity coefficients.
Chemistry
1 answer:
GaryK [48]3 years ago
4 0

Answer:

Attached below

Explanation:

Free energy of mixing = ΔGmix = Gf - Gi

attached below is the required derivation of the

<u>a) Molar Gibbs energy of mixing</u>

ΔGmix = Gf - Gi

hence : ΔGmix = ∩RT ( X1 In X1 + X2 In X2 + X3 In X3 + ------- )

<u>b) molar excess Gibbs energy of mixing</u>

Ni = chemical potential of gas

fi = Fugacity

N°i = Chemical potential of gas when Fugacity = 1

ΔG = RT In ( a2 / a1 )  

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Arrange the following element, lithium, potassium, carbon and fluorine in increasing ionization energy
Juli2301 [7.4K]

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flourine(1681),carbon(1086),lithium(520) and potassium(419)

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4 0
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Read 2 more answers
For the following reaction, 38.3 grams of sulfuric acid are allowed to react with 33.5 grams of calcium hydroxide sulfuric acid(
Likurg_2 [28]

Answer:

What is the maximum amount of calcium sulfate that can be formed? 53.1 grams CaSO4

What is the FORMULA for the limiting reagent? H2SO4

What amount of the excess reagent remains after the reaction is complete? 4.59 grams of Ca(OH)2

Explanation:

Step 1: Data given

Mass of sulfuric acid = 38.3 grams

Molar mass of H2SO4 = 98.08 g/mol

Mass of calcium hydroxide = 33.5 grams

Molar mass of Ca(OH)2 = 74.09 g/mol

Step 2: The balanced equation

H2SO4 + Ca(OH)2 → CaSO4 + 2H2O

Step 3: Calculate moles of H2SO4

moles H2SO4 = mass H2SO4 / molar mass H2SO4

moles H2SO4 = 38.3 grams / 98.08 g/mol

moles H2SO4 = 0.390 moles

Step 4: Calculate moles of Ca(OH)2

moles Ca(OH)2 = 33.5 grams / 74.09 g/mol

moles Ca(OH)2 =0.452 moles

Step 5: Calculate limiting reactant

For 1 mol H2SO4, we need 1 mol of Ca(OH)2 to produce, 1 mol of CaSO4 and 2 mol of H2O

H2SO4 is the limiting reactant. It will completely be consumed (0.390 moles).

Ca(OH)2 is in excess. There will be consumed 0.390 moles

There will remain 0.452 - 0.390 = 0.062 moles

This is 0.062 * 74.09 g/mol = 4.59 grams

Step 6: Calculate moles of calcium sulfate

For 1 mol H2SO4, we need 1 mol of Ca(OH)2 to produce, 1 mol of CaSO4 and 2 mol of H2O

For 0.390 moles of H2SO4, there will be produced 0.390 moles of CaSO4

Step 7: Calculate mass of CaSO4

Mass CaSO4 = moles CaSO4 * molar mass CaSO4

Mass CaSO4 = 0.390 moles * 136.14 g/mol

Mass of CaSO4 = 53.1 grams

7 0
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andrew-mc [135]

Answer:

The correct answer is because the molecular structure.

Explanation:

The difficulty of ammonia and methane to be represented on paper is due to the molecular structure. These compounds have a three-dimensional projection with defined angles. Ammonia presents angles of 109.5º between the atom of Nitrogen and those of Oxygen. The ammonia presents 107.8º between the oxygen atoms.

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Have a nice day!

6 0
3 years ago
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