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Nezavi [6.7K]
3 years ago
11

Enthalpy of atomisation

Chemistry
1 answer:
Softa [21]3 years ago
3 0

Answer:

The enthalpy of atomization is the enthalpy change that accompanies the total separation of all atoms in a chemical substance. This is often represented by the symbol ΔₐₜH or ΔHₐₜ. All bonds in the compound are broken in atomization and none are formed, so enthalpies of atomization are always positive.

Explanation:

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Which of the following has the greatest electronegativity difference between the bonded atoms? View Available Hint(s) Which of t
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Answer: A group 1 alkali metal bonded to fluoride, such as LiF.

Explanation:

Electronegativity is defined as the property of an element to attract a shared pair of electron towards itself. The size of an atom increases as we move down the group because a new shell is added and electron gets added up.

1. A strong acid made of hydrogen and a halogen, such as HCl : A polar covalent bond is defined as the bond which is formed when there is a difference of electronegativities between the atoms. Electronegativity difference = electronegativity of chlorine - electronegativity of hydrogen = 3-2.1= 0.9

2. A group 1 alkali metal bonded to fluoride, such as LiF: Ionic bond is formed when there is complete transfer of electron from a highly electropositive metal to a highly electronegative non metal.

Electronegativity difference = electronegativity of fluorine - electronegativity of lithium= 4-1= 3

3. Carbon bonded to a group 6A (16) nonmetal chalcogen, such as in CO: A polar covalent bond is defined as the bond which is formed when there is a difference of electronegativities between the atoms.

Electronegativity difference = electronegativity of oxygen - electronegativity of carbon= 3.5-2.5= 1.0

4. A diatomic gas, such as nitrogen (N_2): Non-polar covalent bond is defined as the bond which is formed when there is no difference of electronegativities between the atoms.

Electronegativity difference = 0

Thus the greatest electronegativity difference between the bonded atoms is in LiF.

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A 29.8 mL sample of a 0.476 M aqueous hydrocyanic acid solution is titrated with a 0.487 M aqueous barium hydroxide solution. Wh
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Answer:

The pH is 4.76

Explanation:

Step 1: Data given

Volume of a 0.476 M hydrocyanic acid solution = 29.8 mL = 0.0298 L

Volume of 0.487 M barium hydroxide solution = ?

Ka HCN = 6.2 * 10^-10

Step 2: Calculate pH

Hydrocyanic acid is a weak acid.

Barium hydroxide is a strong base.

 

The question asked = the pH BEFORE any base has been added, so we can ignore the base.  

 

To calculate the pH of aweak acid, we need the pKa

HCN ⇔ H+ + CN-

Ka =  [H+][CN-]/[HCN]

⇒ for weak acid: [H+]=[CN-]

Ka = [H+]²/[HCN]

[H+]² = [HCN]*Ka

[H+] = √([HCN]*Ka)

pH = -log(√([HCN]*Ka))

pH = -log(√(0.476 * 6.2*10^-10))

pH = 4.76

The pH is 4.76

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