Answer:
Explanation:
Given that:
Half life = 30 min
Where, k is rate constant
So,
The rate constant, k = 0.0231 min⁻¹
Using integrated rate law for first order kinetics as:
![[A_t]=[A_0]e^{-kt}](https://tex.z-dn.net/?f=%5BA_t%5D%3D%5BA_0%5De%5E%7B-kt%7D)
Where,
![[A_t]](https://tex.z-dn.net/?f=%5BA_t%5D)
is the concentration at time t
![[A_0]](https://tex.z-dn.net/?f=%5BA_0%5D)
is the initial concentration
Given that:
The rate constant, k = 0.0231 min⁻¹
Initial concentration = 7.50 mg
Final concentration = 0.25 mg
Time = ?
Applying in the above equation, we get that:-
Answer:
A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.
Explanation:
We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.
In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.
Answer:
option b is the correct answer
in the periodic table, a set of properties repeats from row to row
