If Phosphorus, P, gained 3 electrons, the net ion charge would be +5 -5 +3 -3
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The hybridization for C in acetylene, HCCH, or C₂H₂ is 'sp'.
Discussion:
There are three different forms of hybridization -
- sp- The first occurs when two carbon atoms are triple linked.
- sp₂- When two carbon atoms are double-bonded to one another, this is known as sp₂.
- sp₃- When a single bond joins two carbon atoms, this is known as sp₃.
In the case of acetylene(HCCH or C₂H₂):
- The carbon atom requires additional electrons to establish four bonds with hydrogen and other carbon atoms in the synthesis of C₂H₂. One 2s₂ pair is consequently transferred to the vacant 2pz orbital. Each carbon has two sp hybrid orbitals after the 2s orbital in each atom combines with one of the 2p orbitals.
- As a result of the atoms' symmetrical alignment in a single plane, C₂H₂ possesses a linear molecular structure. Due to their lower electronegative nature than Hydrogen atoms, all Carbon atoms are situated near the center of the Lewis structure of C₂H₂.
H-C≡C-H
Therefore, it is concluded from the above discussion that the hybridization type of acetylene is 'sp'.
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According to Clausius-Clayperon equation,
is the vapor pressure at boiling point = 760 torr
is the vapor pressure at T_{2} =638.43 torr
Temperature
Δ
Plugging in the values, we get
ln
Therefore, the boiling point of octane = 389 K - 273 =