Answer:
1.52g NaHCO3 were in the original mixture.
Mass percent: 64.1%
Explanation:
When NaHCO3 heats it descomposition occurs as follows:
2 NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g).
The loss in mass is because of the evaporization of CO2 and H2O. As both are in the same porportion, its molar mass is the sum of both compounds (44g/mol + 18g/mol = 62g/mol)
Loss in mass: 74.80g - 74.24g = 0.56g.
In moles:
0.56g * (1mol / 62g) = 0.00903 moles of gas.
As 1 mole of the gases comes from 2 moles of NaHCO3:
<em>Moles NaHCO3:</em>
0.00903 moles of gas * (2 moles NaHCO3 / 1 mole gas) = 0.018 moles NaHCO3.
In grams (Molar mass NaHCO3: 84g/mol):
0.018 moles NaHCO3 * (84g / mol) = 1.52g NaHCO3 were in the original mixture.
The mass of the mixture was:
74.80g - 72.428g = 2.372g
That means mass percent of NaHCO3 is:
(1.52g / 2.372g) * 100 = 64.1%
Answer:
1. The products of this reaction are ZnCl₂ and H₃PO₄.
2. 14.57 g.
Explanation:
<em>1. What would the products of this reaction be?</em>
- The balanced reaction between Zn₃(PO₄)₂ and HCl is represented as:
<em>Zn₃(PO₄)₂ + 6HCl → 3ZnCl₂ + 2H₃PO₄,</em>
It is clear that 1.0 mol of Zn₃(PO₄)₂ reacts with 6.0 mol of HCl to produce 3.0 mol of ZnCl₂ and 2.0 mol of H₃PO₄.
So, the products of this reaction are ZnCl₂ and H₃PO₄.
<em>2. If we produced 13.05 g of H₃PO₄, how many grams of hydrochloric acid would be need to start with?</em>
- Firstly, we should get the no. of moles (n) of 13.05 grams of H₃PO₄:
n = mass/molar mass = (13.05 g)/(97.994 g/mol) = 0.1332 mol.
<u><em>Using cross-multiplication:</em></u>
6.0 mol of HCl needed to produce → 2.0 mol of H₃PO₄, from stichiometry.
??? mol of HCl needed to produce → 0.1332 mol of H₃PO₄.
∴ The no. of moles of HCl needed = (6.0 mol)(0.1332 mol)/(2.0 mol) = 0.3995 mol.
∴ The mass of HCl needed = n*molar mass = (0.3995 mol)(36.46 g/mol) = 14.57 g.
<em>So, the grams of hydrochloric acid would be need to start with = 14.57 g.</em>
Answer:
CN^- is a strong field ligand
Explanation:
The complex, hexacyanoferrate II is an Fe^2+ specie. Fe^2+ is a d^6 specie. It may exist as high spin (paramagnetic) or low spin (diamagnetic) depending on the ligand. The energy of the d-orbitals become nondegenerate upon approach of a ligand. The extent of separation of the two orbitals and the energy between them is defined as the magnitude of crystal field splitting (∆o).
Ligands that cause a large crystal field splitting such as CN^- are called strong field ligands. They lead to the formation of diamagnetic species. Strong field ligands occur towards the end of the spectrochemical series of ligands.
Hence the complex, Fe(CN)6 4− is diamagnetic because the cyanide ion is a strong field ligand that causes the six d-electrons present to pair up in a low spin arrangement.
Answer:
With less energy at higher trophic levels, there are usually fewer organisms as well
Explanation: Organisms tend to be larger in size at higher trophic levels, but their smaller numbers result in less biomass. Biomass is the total mass of organisms at a trophic level.
Considering the definition of ionization energy, the highest ionization energy belongs to the element:
a. Be
b. Ar
c. Cl
Electrons are held in atoms by their attraction to the nucleus, which means that energy is needed to remove an electron from the atom.
You should keep in mind that the electrons of the last layer are always lost, because they are the weakest attracted to the nucleus.
Ionization energy, also called ionization potential, is the necessary energy that must be supplied to a neutral, gaseous, ground-state atom to remove an electron from an atom. When an electron is removed from a neutral atom, a cation with a charge equal to +1 is formed.
In a group, the ionization energy increases upwards because when passing from one element to the bottom, it contains one more layer of electrons. Therefore, the valence layer electrons, being further away from the nucleus, will be less attracted to it and it will cost less energy to pluck them.
In the same period, in general, it increases as you shift to the right. This is because the elements in this way have a tendency to gain electrons and therefore it will cost much more to tear them off than those on the left which, having few electrons in the last layer will cost them much less to lose them.
Considering all the above, from each of the pairs, the highest ionization energy belongs to the element:
a. Be
b. Ar
c. Cl
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