"At constant pressure, the volume of a fixed amount of gas is directly proportional to its absolute temperature." This is -

Chemistry

1 answer:

Lostsunrise [7]3 years ago

6 0

Answer: B

Explanation:

According to Charle's law, at constant pressure the volume of a fixed mass of a ga is directly proportional to its absolute temperature.

At constant pressure, V∝T.

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He rate constant of a reaction is 4.55 × 10−5 l/mol·s at 195°c and 8.75 × 10−3 l/mol·s at 258°c. what is the activation energy o

Xelga [282]

Answer : The activation energy of the reaction is, $17.285\times 10^4kJ/mole$

Solution :

The relation between the rate constant the activation energy is,

$\log \frac{K_2}{K_1}=\frac{Ea}{2.303\times R}\times [\frac{1}{T_1}-\frac{1}{T_2}]$

where,

$K_1$ = initial rate constant = $4.55\times 10^{-5}L/mole\text{ s}$

$K_2$ = final rate constant = $8.75\times 10^{-3}L/mole\text{ s}$

$T_1$ = initial temperature = $195^oC=273+195=468K$

$T_2$ = final temperature = $258^oC=273+258=531K$

R = gas constant = 8.314 kJ/moleK

Ea = activation energy

Now put all the given values in the above formula, we get the activation energy.

$\log \frac{8.75\times 10^{-3}L/mole\text{ s}}{4.55\times 10^{-5}L/mole\text{ s}}=\frac{Ea}{2.303\times (8.314kJ/moleK)}\times [\frac{1}{468K}-\frac{1}{531K}]$