The element that will have the lowest electronegativity is an element with a small number of valence electrons and a large atomic radius.
Electronegativity of an element is the ability or power of that element in a molecule to attract electrons to its Valence electrons. The following are the properties of electronegativity:
- It increases across a period from left to right of the periodic table,
- It decreases down the periodic table groups
- Group 1 elements are the least (lowest) electronegative elements. These elements have the lowest valence electrons with a large atomic radius.
- Group 7 elements are the most electronegative elements.
Atomic radius of elements increase down a group because of a progressive increase in the number of shells occupied by electrons which increases the size. But it decreases across a period because electrons are accommodated within the same shell leading to greater attraction by the protons in the nucleus.
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40×19.32/100=7.7=8×2=16Ca
35.5×34.30/100=12.1=12×2=24Cl
16×46.38/100=7.4=7×2=14O
Answer:
K(48.5°C) = 1.017 E-8 s-1
Explanation:
- CH3Cl + H2O → CH3OH + HCl
at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1
at T2 = 48.5°C (321.5 K) ⇒ K2 = ?
Arrhenius eq:
- K(T) = A e∧(-Ea/RT)
- Ln K = Ln(A) - [(Ea/R)(1/T)]
∴ A: frecuency factor
∴ R = 8.314 E-3 KJ/K.mol
⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)
⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)
(1)/(2):
⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)
⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)
⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)
⇒ Ln (K1/K2) = - 3.422
⇒ K1/K2 = e∧(-3.422)
⇒ (3.32 E-10 s-1)/K2 = 0.0326
⇒ K2 = (3.32 E-10 s-1)/0.0326
⇒ K2 = 1.017 E-8 s-1
