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Ket [755]
3 years ago
14

An isolated atom of a certain element emits light of wavelength 655 nm when the atom falls from its fifth excited state into its

second excited state. The atom emits a photon of wavelength 435 nm when it drops from its sixth excited state into its second excited state. Find the wavelength of the light radiated when the atom makes a transition from its sixth to its fifth excited state.
Chemistry
1 answer:
dangina [55]3 years ago
6 0

Answer:

\frac{1}{\lambda_{6-5}} \approx 752nm

Explanation:

From the question we are told that

Light wavelength  \lambda_l=655nm

Light wavelength atom fall x_L=5th-2nd

Photon wavelength  \lambda_p=435nm

Photon wavelength atom fall x_P=^th-2nd

Generally the equation for the reciprocal of wavelength of emitted photon is is mathematically given by

\frac{1}{\lambda}=R(\frac{1}{ \lambda _f^2}-\frac{1}{\lambda _i^2} )

Therefore for initial drop of 5th to 2nd

\frac{1}{\lambda_{5-2}}=R(\frac{1}{2^2}-\frac{1}{5^2} )

Therefore for initial drop of 6th to 2nd

\frac{1}{\lambda_{6-2}}=R(\frac{1}{2^2}-\frac{1}{6^2} )

Generally we subtract (5th to 2nd) from (6th to 2nd)

\frac{1}{\lambda_{5-2}}-   \frac{1}{\lambda_{6-2}}=R(\frac{1}{2^2}-\frac{1}{5^2} )-\frac{1}R(\frac{1}{2^2}-\frac{1}{6^2} )

\frac{1}{\lambda_{5-2}}-   \frac{1}{\lambda_{6-2}}=R(\frac{1}{5^2}-\frac{1}{6^2} )

\frac{1}{\lambda_{5-2}}-   \frac{1}{\lambda_{6-2}}=\frac{1}{\lambda_{5-6}}

\frac{1}{\lambda_{5-6}}=\frac{1}{4350nm}-\frac{1}{655nm}

\frac{1}{\lambda_{5-6}}=1.33*10^{-3}

Therefore for 6th to 5th stage is mathematically given by

\frac{1}{\lambda_{6-5}}=(1.33*10^{-3})^{-1}

\frac{1}{\lambda_{6-5}}=751.879nm

\frac{1}{\lambda_{6-5}} \approx 752nm

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