<span>The particles are far apart from each other.</span>
Direct electron transfer from a a singlet reduced species to a triplet oxidizing species is quantum-mechanically forbidden.
<h3><u>Transfer from singlet to triplet:</u></h3>
- Either an excited singlet state or an excited triplet state will occur when an electron in a molecule with a singlet ground state is stimulated (through radiation absorption) to a higher energy level.
- All electron spins in a molecule electronic state known as a singlet are coupled.
- In other words, the ground state electron and the stimulated electron's spin are still coupled (a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle).
- The excited electron and ground state electron are parallel in a triplet state because they are no longer coupled (same spin).
- It is less likely that a triplet state would arise when the molecule absorbs radiation since excitation to a triplet state necessitates an additional "forbidden" spin transfer.
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Plant: leaf tissue
Human: lungs
You need the set of reactions that goes from ammonia to nitric acid.
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1) 4NH3(g)+5O2(g)-->4NO(g)+6H2O(g)
2) 2NO(g)+O2(g)-->2NO2(g)
3) 3NO2(g)+H2O(l)-->2HNO3(aq)+NO(g)
State the ratio of moles of HNO3 to NH3:
4 moles of NH3 produce 4 mole of NO,
4 moles of NO produce 4 moles of NO2
4 moles of NO2 produce 4 * (2 / 3) moles of HNO3 = 8/3 moles of HNO3.
=> (8/3) moles HNO3 : 4 moles NH3
Calculate the number of moles of HNO3 in 900.00 l of 0.140 M solution
M = n / V => n = M * V = 0.140 M * 900.00 liter = 126 moles HNO3
Use proportions:
(</span><span>8/3) moles HNO3 / 4 moles NH3 = 126 moles HNO3 / x
=> x = 126 moles HNO3 * 4 moles NH3 / (8/3 moles HNO3) = 189 moles NH3
Convert moles to grams:
molar mass NH3 = 14 g/mol + 3 * 1g/mol = 17 g/mol
mass in grams = number of moles * molar mass = 189 moles * 17 g/mol = 3213 g
Answer: 3213 g.
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