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nika2105 [10]
3 years ago
13

A 1.53-L sample of gaseous sulfur dioxide has a pressure of 5600

Chemistry
1 answer:
andriy [413]3 years ago
5 0
5600 why because you take away and then you add then yeah
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Need help with 14 and 16 pls asap!! this is my friends test and im taking it tomorrow!!
marin [14]

Answer:

Q14: 17,140 g = 17.14 kg.

Q16: 504 J.

Explanation:

<u><em>Q14:</em></u>

  • To solve this problem, we can use the relation:

<em>Q = m.c.ΔT,</em>

where, Q is the amount of heat absorbed by ice (Q = 3600 x 10³ J).

m is the mass of the ice (m = ??? g).

c is the specific heat of the ice (c of ice = 2.1 J/g.°C).

ΔT is the difference between the initial and final temperature (ΔT = final T - initial T = 100.0°C - 0.0°C = 100.0°C).

∵ Q = m.c.ΔT

∴ (3600 x 10³ J) = m.(2.1 J/g.°C).(100.0°C)

∴ m = (3600 x 10³ J)/(2.1 J/g.°C).(100.0°C) = 17,140 g = 17.14 kg.

<u><em>Q16:</em></u>

  • To solve this problem, we can use the relation:

<em>Q = m.c.ΔT,</em>

where, Q is the amount of heat absorbed by ice (Q = ??? J).

m is the mass of the ice (m = 12.0 g).

c is the specific heat of the ice (c of ice = 2.1 J/g.°C).

ΔT is the difference between the initial and final temperature (ΔT = final T - initial T = 0.0°C - (-20.0°C) = 20.0°C).

∴ Q = m.c.ΔT = (12.0 g)(2.1 J/g.°C)(20.0°C) = 504 J.

6 0
3 years ago
A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would
Olenka [21]

Answer:

C. Ca_3(PO_4)_2  will precipitate out first

the percentage of Ca^{2+}remaining =  12.86%

Explanation:

Given that:

A solution contains:

[Ca^{2+}] = 0.0440 \ M

[Ag^+] = 0.0940 \ M

From the list of options , Let find the dissociation of Ag_3PO_4

Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}

where;

Solubility product constant Ksp of Ag_3PO_4 is 8.89 \times 10^{-17}

Thus;

Ksp = [Ag^+]^3[PO_4^{3-}]

replacing the known values in order to determine the unknown ; we have :

8.89 \times 10 ^{-17}  = (0.0940)^3[PO_4^{3-}]

\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}  = [PO_4^{3-}]

[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}

[PO_4^{3-}] =1.07 \times 10^{-13}

The dissociation  of Ca_3(PO_4)_2

The solubility product constant of Ca_3(PO_4)_2  is 2.07 \times 10^{-32}

The dissociation of Ca_3(PO_4)_2   is :

Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}

Thus;

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33} = (0.0440)^3  [PO_4^{3-}]^2

\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}=   [PO_4^{3-}]^2

[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}

[PO_4^{3-}]^2 = 2.43 \times 10^{-29}

[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}

[PO_4^{3-}] =4.93 \times 10^{-15}

Thus; the phosphate anion needed for precipitation is smaller i.e 4.93 \times 10^{-15} in Ca_3(PO_4)_2 than  in  Ag_3PO_4  1.07 \times 10^{-13}

Therefore:

Ca_3(PO_4)_2  will precipitate out first

To determine the concentration of [Ca^+] when  the second cation starts to precipitate ; we have :

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33}  = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2

[Ca^{2+}]^3 =  \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}

[Ca^{2+}]^3 =1.808 \times 10^{-7}

[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}

[Ca^{2+}] =0.00566

This implies that when the second  cation starts to precipitate ; the  concentration of [Ca^{2+}] in the solution is  0.00566

Therefore;

the percentage of Ca^{2+}  remaining = concentration remaining/initial concentration × 100%

the percentage of Ca^{2+} remaining = 0.00566/0.0440  × 100%

the percentage of Ca^{2+} remaining = 0.1286 × 100%

the percentage of Ca^{2+}remaining =  12.86%

5 0
3 years ago
Determine the empirical and molecular formula for chrysotile asbestos. Chrysotile has the following percent composition: 28.03%
nlexa [21]

<u>Answer:</u> The empirical and molecular formula of chrysotile is Mg_3Si_2H_3O_4 and Mg_6Si_4H_6O_{16}

<u>Explanation:</u>

We are given:

Percentage of Mg = 28.03 %

Percentage of Si = 21.60 %

Percentage of H = 1.16 %

Percentage of O = 49.21 %

Let the mass of compound be 100 g. So, percentages given are taken as mass.

Mass of Mg = 28.03 g

Mass of Si = 21.60 g

Mass of H = 1.16 g

Mass of O = 49.21 g

To formulate the empirical formula, we need to follow some steps:

  • <u>Step 1:</u> Converting the given masses into moles.

Moles of Magnesium = \frac{\text{Given mass of Magnesium}}{\text{Molar mass of Magnesium}}=\frac{28.03g}{24g/mole}=1.17moles

Moles of Silicon = \frac{\text{Given mass of Silicon}}{\text{Molar mass of Silicon}}=\frac{21.06g}{28g/mole}=0.752moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{1.16g}{1g/mole}=1.16moles

Moles of Oxygen = \frac{\text{Given mass of oxygen}}{\text{Molar mass of oxygen}}=\frac{49.21g}{16g/mole}=3.07moles

  • <u>Step 2:</u> Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.752 moles.

For Magnesium = \frac{1.17}{0.752}=1.5

For Silicon = \frac{0.752}{0.752}=1

For Hydrogen = \frac{1.16}{0.752}=1.5

For Oxygen = \frac{3.07}{0.485}=4.08\approx 4

To convert the mole ratios into whole numbers, we multiply individual mole ratios by 2

Mole ratio of Magnesium = (2 × 1.5) = 3

Mole ratio of Silicon = (2 × 1) = 2

Mole ratio of Hydrogen = (2 × 1.5) = 3

Mole ratio of Oxygen = (2 × 4) = 8

  • <u>Step 3:</u> Taking the mole ratio as their subscripts.

The ratio of Mg : Si : H : O = 3 : 2 : 3 : 8

The empirical formula for the given compound is Mg_3Si_2H_3O_8

For determining the molecular formula, we need to determine the valency which is multiplied by each element to get the molecular formula.

The equation used to calculate the valency is :

n=\frac{\text{Molecular mass}}{\text{Empirical mass}}

We are given:

Mass of molecular formula = 520.8 g/mol

Mass of empirical formula = [(24 × 3) + (28 × 2) + (1 × 3) + (16 × 8)] = 259 g/mol

Putting values in above equation, we get:

n=\frac{520.8g/mol}{259g/mol}=2

Multiplying this valency by the subscript of every element of empirical formula, we get:

Mg_{(3\times 2)}Si_{(2\times 2)}H_{(3\times 2)}O_{(8\times 2)}=Mg_6Si_4H_6O_{16}

Hence, the empirical and molecular formula of chrysotile is Mg_3Si_2H_3O_4 and Mg_6Si_4H_6O_{16}

5 0
3 years ago
Complete combustion of 7.40 g of a hydrocarbon produced 22.4 g of CO2 and 11.5 g of H2O. What is the empirical formula for the h
cluponka [151]
<span>C2H5 First, you need to figure out the relative ratios of moles of carbon and hydrogen. You do this by first looking up the atomic weight of carbon, hydrogen, and oxygen. Then you use those atomic weights to calculate the molar masses of H2O and CO2. Carbon = 12.0107 Hydrogen = 1.00794 Oxygen = 15.999 Molar mass of H2O = 2 * 1.00794 + 15.999 = 18.01488 Molar mass of CO2 = 12.0107 + 2 * 15.999 = 44.0087 Now using the calculated molar masses, determine how many moles of each product was generated. You do this by dividing the given mass by the molar mass. moles H2O = 11.5 g / 18.01488 g/mole = 0.638361 moles moles CO2 = 22.4 g / 44.0087 g/mole = 0.50899 moles The number of moles of carbon is the same as the number of moles of CO2 since there's just 1 carbon atom per CO2 molecule. Since there's 2 hydrogen atoms per molecule of H2O, you need to multiply the number of moles of H2O by 2 to get the number of moles of hydrogen. moles C = 0.50899 moles H = 0.638361 * 2 = 1.276722 We can double check our math by multiplying the calculated number of moles of carbon and hydrogen by their respective atomic weights and see if we get the original mass of the hydrocarbon. total mass = 0.50899 * 12.0107 + 1.276722 * 1.00794 = 7.400185 7.400185 is more than close enough to 7.40 given rounding errors, so the double check worked. Now to find the empirical formula we need to find a ratio of small integers that comes close to the ratio of moles of carbon and hydrogen. 0.50899 / 1.276722 = 0.398669 0.398669 is extremely close to 4/10, so let's reduce that ratio by dividing both top and bottom by 2 giving 2/5. Since the number of moles of carbon was on top, that ratio implies that the empirical formula for this unknown hydrocarbon is C2H5</span>
3 0
3 years ago
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