Answer:
12.6.
Explanation:
- We should calculate the no. of millimoles of KOH and HCl:
no. of millimoles of KOH = (MV)KOH = (0.183 M)(45.0 mL) = 8.235 mmol.
no. of millimoles of HCl = (MV)HCl = (0.145 M)(35.0 mL) = 5.075 mmol.
- It is clear that the no. of millimoles of KOH is higher than that of HCl:
So,
[OH⁻] = [(no. of millimoles of KOH) - (no. of millimoles of HCl)] / (V total) = (8.235 mmol - 5.075 mmol) / (80.0 mL) = 0.395 M.
∵ pOH = -log[OH⁻]
∴ pOH = -log(0.395 M) = 1.4.
∵ pH + pOH = 14.
∴ pH = 14 - pOH = 14 - 1.4 = 12.6.
Explanation:
(a) The given data is as follows.
Load applied (P) = 1000 kg
Indentation produced (d) = 2.50 mm
BHI diameter (D) = 10 mm
Expression for Brinell Hardness is as follows.
HB = ![\frac{2P}{\pi D [D - \sqrt{(D^{2} - d^{2})}]}](https://tex.z-dn.net/?f=%5Cfrac%7B2P%7D%7B%5Cpi%20D%20%5BD%20-%20%5Csqrt%7B%28D%5E%7B2%7D%20-%20d%5E%7B2%7D%29%7D%5D%7D)
Now, putting the given values into the above formula as follows.
HB = = ![\frac{2 \times 1000 kg}{3.14 \times 10 mm [D - \sqrt{((10 mm)^{2} - (2.50)^{2})}]}](https://tex.z-dn.net/?f=%5Cfrac%7B2%20%5Ctimes%201000%20kg%7D%7B3.14%20%5Ctimes%2010%20mm%20%5BD%20-%20%5Csqrt%7B%28%2810%20mm%29%5E%7B2%7D%20-%20%282.50%29%5E%7B2%7D%29%7D%5D%7D)
= 
= 200
Therefore, the Brinell HArdness is 200.
(b) The given data is as follows.
Brinell Hardness = 300
Load (P) = 500 kg
BHI diameter (D) = 10 mm
Indentation produced (d) = ?
d = ![\sqrt{(D^{2} - [D - \frac{2P}{HB} \pi D]^{2})}](https://tex.z-dn.net/?f=%5Csqrt%7B%28D%5E%7B2%7D%20-%20%5BD%20-%20%5Cfrac%7B2P%7D%7BHB%7D%20%5Cpi%20D%5D%5E%7B2%7D%29%7D)
= ![\sqrt{(10 mm)^{2} - [10 mm - \frac{2 \times 500 kg}{300 \times 3.14 \times 10 mm}]^{2}}](https://tex.z-dn.net/?f=%5Csqrt%7B%2810%20mm%29%5E%7B2%7D%20-%20%5B10%20mm%20-%20%5Cfrac%7B2%20%5Ctimes%20500%20kg%7D%7B300%20%5Ctimes%203.14%20%5Ctimes%2010%20mm%7D%5D%5E%7B2%7D%7D)
= 4.46 mm
Hence, the diameter of an indentation to yield a hardness of 300 HB when a 500-kg load is used is 4.46 mm.
Answer:
A restoration
Explanation:
the action of returning something to a former owner, place, or condition.
Answer:
Explanation:1. NaNH2 (1-Butene)
CH3CH2CH2CH2Cl --------------> CH3CH2CH=CH2 + HCl (elimination reaction)
2. Br2, CCl4
CH3CH2CH=CH2 ---------------> CH3CH2CH(Br)CH2Br (Simple addition Reaction)
3. NaNH2 (1-Butyne)
CH3CH2CH(Br)CH2Br ----------------> CH3CH2C≡CH + 2HBr
Sodamide (NaNH2) is a very strong base and generally results in Terminal Alkynes when treated with Vicinal Dihalides.
Alcoholic KOH on the other hand results in the formation of Alkynes with triple bonds in the middle of the molecule.
