Answer:
The four resonance structures of the phenoxide ion are shown in the image attached
The conjugate base of cyclohexanol has only one resonance contributor, while
the conjugate base of phenol has four resonance contributors.
Explanation:
In organic chemistry, it is known that structures are more stable if they possess more resonance contributors. The greater the number of contributing canonical structures, the more stable the organic specie. Since the phenoxide ion has four contributing canonical structures, it is quite much more stable than cyclohexanol having only one contributing structure to its conjugate base. Hence the PKa(acid dissociation constant) of phenol is lesser than that of cyclohexanol. The conjugate base of phenol is stabilized by resonance.
Since the container of the gas is rigid, the volume of the gas will remain constant. Therefore, when the number of particles were decreased in half then the pressure will also be half of the original given they both are subjected to the same temperature.
PV = nRT
V, T and R are constants so they can be lumped together to a constant k.
P/n = k
P1/n1 = P2/n2
since n2 = n1/2
P1/n1 = P2/<span>n1/2</span>
P2 = P1/2
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When Cr dissolves in 1 M H₂Cr₂O₇
Cr(s) ⇄ Cr³⁺ + 3 e⁻
Cr₂O₇²⁻ + 14 H⁺ + 6 e⁻ ⇄ 2 Cr³⁺ + 7 H₂O
by multiplying the first equation by 2 and add the 2 equations;
The balanced redox reaction will be:
2 Cr(s) + Cr₂O₇²⁻(aq) + 14 H⁺(aq) → 4 Cr³⁺(aq) + 7 H₂O(l)
Depending if the reaction is a reversible or an irreversible one, the direction of the arrow will point in one direction or 2 directions from reactants to products.
