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kari74 [83]
3 years ago
5

You can fit 25 drops of substance X on a penny and 12 drops of substance Y on a different penny. Explain the difference in terms

of strength of IMF.
Chemistry
1 answer:
kati45 [8]3 years ago
5 0

Answer:

In the experiment performed involving the number of liquid drops that a penny can hold, 25 drops of substance X can fit in a penny while only 12 drops of substance Y can fit on another penny because, substance X is more viscous than substance Y. Thus, the intermolecular forces present in substance X are stronger than those present in substance Y.

Explanation:

Intermolecular forces (IMF) are the forces which exist between the neighboring molecules of a a substance. These forces, though weaker than intramolecular forces which acts between neighboring atoms, they still are responsible for several differences in the physical properties of substances with comparatively similar molecular masses.

The three major types of intermolecular forces are, hydrogen bonding, dipole–dipole interactions and  London dispersion forces.

The existence of intermolecular forces in molecules of substances results in increase in melting and boiling points, surface tension,  capillary action, viscosity, as well as surface area of substances,

Viscosity, which is the resistance to flow offered by a liquid increases with increase in the intermolecular forces between the molecules of a liquid.

In the experiment performed involving the number of liquid drops that a penny can hold, 25 drops of substance X can fit in a penny while only 12 drops of substance Y can fit on another penny because, substance X is more viscous than substance Y. Thus, the intermolecular forces present in substance X are stronger than those present in substance Y.

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Excess magnesium reacts with 165.0 grams of hydrochloric acid in a single displacement reaction.
JulsSmile [24]

Answer:

The volume of hydrogen gas produced will be approximately 50.7 liters under STP.

Explanation:

Relative atomic mass data from a modern periodic table:

  • H: 1.008;
  • Cl: 35.45.

Magnesium is a reactive metal. It reacts with hydrochloric acid to produce

  • Hydrogen gas \rm H_2, and
  • Magnesium chloride, which is a salt.

The chemical equation will be something like

\rm ?\;Mg\;(s) + ?\;HCl \;(aq)\to ?\;H_2 \;(g)+ [\text{Formula of the Salt}],

where the coefficients and the formula of the salt are to be found.

To determine the number of moles of \rm H_2 that will be produced, first find the formula of the salt, magnesium chloride.

Magnesium is a group 2 metal. The oxidation state of magnesium in compounds tends to be +2.

On the other hand, the charge on each chloride ion is -1. Each magnesium ion needs to pair up with two chloride ions for the charge to balance in the salt, magnesium chloride. The formula for the salt will be \rm MgCl_2.

\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ ?\;MgCl_2\;(aq).

Balance the equation. \rm MgCl_2 contains the largest number of atoms among all species in this reaction. Start by setting its coefficient to 1.

\rm ?\;Mg\;(s) + ?\;HCl\;(aq) \to ?\;H_2 \;(g)+ {\bf 1\;MgCl_2}\;(aq).

The number of \rm Mg and \rm Cl atoms shall be the same on both sides. Therefore

\rm {\bf 1\;Mg}\;(s) + {\bf 2\;HCl}\;(aq) \to ?\;H_2 \;(g)+ {1\;\underset{\wedge}{Mg}\underset{\wedge}{Cl_2}}\;(aq).

The number of \rm H atoms shall also conserve. Hence the equation:

\rm {1\;Mg}\;(s) + {2\;\underset{\wedge}{H}Cl}\;(aq) \to {\bf 1\;H_2 \;(g)}+ {1\;MgCl_2}\;(aq).

How many moles of HCl are available?

M(\rm HCl) = 1.008 + 35.45 = 36.458\;g\cdot mol^{-1}.

\displaystyle n({\rm HCl}) = \frac{m(\text{HCl})}{M(\text{HCl})} = \rm \frac{165.0\;g}{36.458\;g\cdot mol^{-1}} = 4.52576\;mol.

How many moles of Hydrogen gas will be produced?

Refer to the balanced chemical equation, the coefficient in front of \rm HCl is 2 while the coefficient in front of \rm H_2 is 1. In other words, it will take two moles of \rm HCl to produce one mole of \rm H_2. \rm 4.52576\;mol of \rm HCl will produce only one half as much \rm H_2.

Alternatively, consider the ratio between the coefficient in front of \rm H_2 and \rm HCl is:

\displaystyle \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}.

\displaystyle n(\text{H}_2) = n(\text{HCl})\cdot \frac{n(\text{H}_2)}{n(\text{HCl})} = \frac{1}{2}\;n(\text{HCl}) = \rm \frac{1}{2}\times 4.52576\;mol = 2.26288\;mol.

What will be the volume of that many hydrogen gas?

One mole of an ideal gas occupies a volume of 22.4 liters under STP (where the pressure is 1 atm.) On certain textbook where STP is defined as \rm 1.00\times 10^{5}\;Pa, that volume will be 22.7 liters.

V(\text{H}_2) = \rm 2.26288\;mol\times 22.4\;L\cdot mol^{-1} = 50.69\; L, or

V(\text{H}_2) = \rm 2.26288\;mol\times 22.7\;L\cdot mol^{-1} = 51.37\; L.

The value "165.0 grams" from the question comes with four significant figures. Keep more significant figures than that in calculations. Round the final result to four significant figures.

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