The question is: Calculate the molar fractions of the components of a solution made up of: 250 g of water, 50 g of acetic acid and 25 g of sodium chloride.
Answer: The mole fraction of water, acetic acid and sodium chloride is 0.916, 0.054, and 0.028.
Explanation:
As number of moles is the mass of substance divided by its molar mass.
Therefore, moles of given species are calculated as follows.
The number of moles of water (molar mass = 18 g/mol):
![Moles = \frac{mass}{molar mass}\\= \frac{250 g}{18 g/mol}\\= 13.88 mol](https://tex.z-dn.net/?f=Moles%20%3D%20%5Cfrac%7Bmass%7D%7Bmolar%20mass%7D%5C%5C%3D%20%5Cfrac%7B250%20g%7D%7B18%20g%2Fmol%7D%5C%5C%3D%2013.88%20mol)
The number of moles of acetic acid (molar mass = 60.052 g/mol):
![Moles = \frac{mass}{molar mass}\\= \frac{50 g}{60.052 g/mol}\\= 0.832 mol](https://tex.z-dn.net/?f=Moles%20%3D%20%5Cfrac%7Bmass%7D%7Bmolar%20mass%7D%5C%5C%3D%20%5Cfrac%7B50%20g%7D%7B60.052%20g%2Fmol%7D%5C%5C%3D%200.832%20mol)
The number of moles of sodium chloride (molar mass = 58.44 g/mol):
![Moles = \frac{mass}{molar mass}\\= \frac{25 g}{58.44 g/mol}\\= 0.427 mol](https://tex.z-dn.net/?f=Moles%20%3D%20%5Cfrac%7Bmass%7D%7Bmolar%20mass%7D%5C%5C%3D%20%5Cfrac%7B25%20g%7D%7B58.44%20g%2Fmol%7D%5C%5C%3D%200.427%20mol)
Therefore, mole fraction of each component is calculated as follows.
Mole fraction of water:
![Mole fraction = \frac{moles of water}{Total moles}\\= \frac{13.88}{13.88 + 0.832 + 0.427}\\= \frac{13.88}{15.139}\\= 0.916](https://tex.z-dn.net/?f=Mole%20fraction%20%3D%20%5Cfrac%7Bmoles%20of%20water%7D%7BTotal%20moles%7D%5C%5C%3D%20%5Cfrac%7B13.88%7D%7B13.88%20%2B%200.832%20%2B%200.427%7D%5C%5C%3D%20%5Cfrac%7B13.88%7D%7B15.139%7D%5C%5C%3D%200.916)
Mole fraction of acetic acid:
![Mole fraction = \frac{moles of water}{Total moles}\\= \frac{0.832}{13.88 + 0.832 + 0.427}\\= \frac{0.832}{15.139}\\= 0.054](https://tex.z-dn.net/?f=Mole%20fraction%20%3D%20%5Cfrac%7Bmoles%20of%20water%7D%7BTotal%20moles%7D%5C%5C%3D%20%5Cfrac%7B0.832%7D%7B13.88%20%2B%200.832%20%2B%200.427%7D%5C%5C%3D%20%5Cfrac%7B0.832%7D%7B15.139%7D%5C%5C%3D%200.054)
Mole fraction of NaCl:
![Mole fraction = \frac{moles of water}{Total moles}\\= \frac{0.427}{13.88 + 0.832 + 0.427}\\= \frac{0.427}{15.139}\\= 0.028](https://tex.z-dn.net/?f=Mole%20fraction%20%3D%20%5Cfrac%7Bmoles%20of%20water%7D%7BTotal%20moles%7D%5C%5C%3D%20%5Cfrac%7B0.427%7D%7B13.88%20%2B%200.832%20%2B%200.427%7D%5C%5C%3D%20%5Cfrac%7B0.427%7D%7B15.139%7D%5C%5C%3D%200.028)
Thus, we can conclude that mole fraction of water, acetic acid and sodium chloride is 0.916, 0.054, and 0.028.