Identify NaOH (aq) + HNO3(aq) → NaNO3(aq) + H2O(1)
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Answer:
- <em>The solution that has the highest concentration of hydroxide ions is </em><u>d. pH = 12.59.</u>
Explanation:
You can solve this question using just some chemical facts:
- pH is a measure of acidity or alkalinity: the higher the pH the lower the acidity and the higher the alkalinity.
- The higher the concentration of hydroxide ions the lower the acidity or the higher the alkalinity of the solution, this is the higher the pH.
Hence, since you are asked to state the solution with the highest concentration of hydroxide ions, you just pick the highest pH. This is the option d, pH = 12.59.
These mathematical relations are used to find the exact concentrations of hydroxide ions:
- pH + pOH = 14 ⇒ pOH = 14 - pH
- pOH = - log [OH⁻] ⇒
Then, you can follow these calculations:
Solution pH pOH [OH⁻]
a. 3.21 14 - 3.21 = 10.79 antilogarithm of 10.79 = 1.6 × 10⁻¹¹
b. 7.00 14 - 7.00 = 7.00 antilogarithm of 7.00 = 10⁻⁷
c. 7.93 14 - 7.93 = 6.07 antilogarithm of 6.07 = 8.5 × 10⁻⁷
d. 12.59 14 - 12.59 = 1.41 antilogarithm of 1.41 = 0.039
e. 9.82 14 - 9.82 = 4.18 antilogarithm of 4.18 = 6.6 × 10⁻⁵
From which you see that the highest concentration of hydroxide ions is for pH = 12.59.
19.7 litre volume of carbon dioxide gas at 22.0o C and 102 kPa can be collected over water.
<h3>What is vapour pressure?</h3>Vapour pressure is a measure of the tendency of a material to change into the gaseous or vapour state, and it increases with temperature.
Moles of Butane = mass in grams / molar mass = 11.6 / 58.12 = 0.2
Volume of (V) = 40 liter
Temperature (T) = 22°C = 22 + 273 = 295 K
Pressure (P) = 102 kPa = 102 / 101.325 = 1.007 atm
Moles of (n) can be calculated by ideal gas equation.
PV = nRT
n = 1.007 40 ÷ 0.0821 295 = 1.663
Balanced chemical reaction;
2 + 13
---> 8
+ 10
From reaction;
13 moles require 2 moles
So, 1.663 moles will require = 2 x 1.663 ÷13 = 0.256 moles of
Thus is a limiting reagent. So it will drive the yield of
.
Moles of produced = (8/2) 0.2 = 0.8 moles
Pressure of (P) = 102 - 2.24 = 99.76 kPa = 99.76 ÷ 101.325 = 0.985 atm
Applying the ideal gas equation for ,
PV = nRT
0.985 V = 0.8 0.0821 x 295
V = 19.7 liter
The volume of produced = 19.7 liter.
Learn more about the vapour pressure here:
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