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sdas [7]
3 years ago
13

A chemist added an excess of sodium sulfate to a solution of a soluble barium compound to precipitate all of the barium ions as

barium sulfate, BaSO4. How many grams of barium ions are in a 441-mg sample of the barium compound if a solution of the sample gave 403 mg BaSO4 precipitate? What is the mass percentage of barium compound?
Chemistry
1 answer:
grigory [225]3 years ago
8 0

Answer:

  259.497 mg,   58.84%

Explanation:

BaSO₄ → Ba²⁺ + SO₄²⁻

to calculate the mole of BaSO₄

mole BaSO₄ = mass given / molar mass = 403 mg / 233.38 g/mol = 1.7268 mol

comparing the mole ratio

1.7268 mol of BaSO₄ yields 1.7268 mol of Ba²⁺

403 mg BaSO₄  yields     ( 1.7268 × 137.327 ) where 137.327 is the molar mass of Barium mol of Ba²⁺

441 mg BaSO₄  will yield   ( 1.7268 × 137.327  × 441 mg ) / 403 mg = 259 .497 mg

mas percentage of the Barium compound = 259 .497 mg / 441 mg × 100 = 58.84%

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Answer:

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Explanation:

The last reaction is:

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As the amount of BaCl₂ is the maximum possible to produce BaSO₄, the moles of BaCl₂ must be the same than moles of Na₂SO₄.

0,502 moles of BaCl₂ ≡ 0,502 moles of Na₂SO₄

These moles of Na₂SO₄ comes from:

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As the reaction is in stoichiometric amounts, moles of Na are twice the moles of Na₂SO₄

0,502 moles of Na₂SO₄ ×\frac{2molesNa}{1moleNa_{2}SO_{4}}× 22,99 g/mole = 23,08 g of Na

Molar percent of sodium in original mixture is:

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I hope it helps

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