Answer: Theoretical Yield = 0.2952 g
Percentage Yield = 75.3%
Explanation:
Calculation of limiting reactant:
n-trans-cinnamic acid moles = (142mg/1000) / 148.16 = 9.584*10⁻⁴ mol
pyridium tribromide moles = (412mg/1000) / 319.82= 1.288*10⁻³ mol
- n-trans-cinnamic acid is the limiting reactant
The molar ratio according to the equation mentioned is equals to 1:1
The brominated product moles is also = 9.584*10⁻⁴ mol
Theoretical yield = (9.584*10⁻⁴ mol) * (Mr of brominated product)
= (9.584*10⁻⁴ mol) * (307.97) = 0.2952 g
Percentage Yield is : Actual Yield / Theoretical Yield = 0.2223/0.2952
= 75.3%
In thermal cracking, high temperatures (typically in the range of 450°C to 750°C) and pressures (up to about 70 atmospheres) are used to break the large hydrocarbons into smaller ones. Thermal cracking gives mixtures of products containing high proportions of hydrocarbons with double bonds - alkenes.
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<u><em>The process of how we would obtain </em></u><u><em>ethanal</em></u><u><em> </em></u><u><em>free</em></u><u><em> from ethanol is described in the explanations below. </em></u>
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- In Chemistry, Ethanol undergoes oxidation in the presence of sodium dichromate plus sulphuric acid to yield ethanal and water.
The procedure for achieving this in the laboratory is as follows;
- Step 1; Measure a quantity of a solution of sodium dichromate acidified in a dilute sulphuric acid and pour into a test tube.
- Step 2; Add excess <em>ethanol</em>. This is because if we don't do so there will be plenty of oxidizing agent to carry out a second operation which changes the aldehyde to ethanoic acid. However, we need only the aldehyde.
- Step 3; When the aldehyde ethanal begins to form which will be evident by the change in the colour of solution from <em>orange to green</em>, then the mixture should be distilled from the test tube and tbethe aldehyde collevted so that it doesn't undergo additional oxidation into ethanoic acid.
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