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belka [17]
3 years ago
12

Why is it necessary to maintain excess bromine in the reaction mixture with trans-cinnamic acid and bromine

Chemistry
1 answer:
DerKrebs [107]3 years ago
4 0

Answer:

It is necessary because Trans-cinnamic is a limiting reagent in the mixture reaction while Bromine is the excess reagent

Explanation:

It is necessary to maintain excess bromine in the reaction mixture because Bromine is the excess reagent in the reaction mixture and if it's quantity is less it would consume the limiting reagent ( Trans-cinnamic ) completely . hence Bromine should maintain excess quantity in the reaction mixture

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Increasing the volume of the vessel

Explanation:

By the Le Chatelier's principle, if a system in equilibrium suffer a variation that disturbs the equilibriu, the reaction shift in the way to minimize the pertubation and re-establish the equilibrium.

For a variation in pressure, when it increases, the reaction shift for the smallest of gas volume, and if decreases, the reaction will shift for the large gas volume. So, for the reaction given, the products have the large amount of gas, so by decreasing the pressure, more products will be formed, and the amount of NH₄HS will reduce. To decrease the pressure, we can increase the volume of the vessel: for the ideal gas equation (PV= nRT), pressure and volume are indirectly proportional.

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Explanation:

Meso compounds are optically inactive stereoisomers. Despite of having chiral carbon, they do not show  optical activity because it has a plane of symmetry in its structure itself. It is superposable on its mirror image.

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