Yes they can have origins in nature. A bunch of the elements on the periodic table are chemicals and this are basic substances and cannot be man made.
The answer should be D, cells can only create an identical copy of the original cell.
Complete Question
A sample of aluminum, which has a specific heat capacity of 0.897 JB loc ! is put into a calorimeter (see sketch at right) that contains 200.0 g of water. The aluminum sample starts off at 85.6 °C and the temperature of the water starts off at 16.0 °C. When the temperature of the water stops changing it's 20.1 °C. The pressure remains constant at 1 atm. Calculate the mass of the aluminum sample.
Answer:

Explanation:
From the question we are told that:
Heat Capacity 
Mass of water 
Initial Temperature of Aluminium 
Initial Temperature of Water 
Final Temperature of Water 
Generally
Heat loss=Heat Gain
Therefore


The answer is B Solubility Increases