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Sulfonation of benzene has the following mechanism: (1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3 [fast] (2) SO3 + C6H6 → H(C6H5+)SO3− [slow]

ziro4ka [17]

Question is incomplete, complete question is as follows :

Complete Question : .Sulfonation of benzene has the following mechanism:

(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3

[fast]

(2) SO3 + C6H6 → H(C6H5+)SO3−

[slow]

(3) H(C6H5+)SO3− + HSO4− → C6H5SO3− + H2SO4

[fast]

(4) C6H5SO3− + H3O+ → C6H5SO3H + H2O

[fast]

write the overall rate law for the initial rate of the reaction as a fraction.

Rate=k(________/_________)

Answer:

The overall rate law for the initial reaction is = $k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]$

Explanation :

Frist of all, all the common terms are cancelled out and written the overall reaction.

As we know that the rate depednant step is the slowest step of the reaction, rate law is :

rate = $k_{2} [SO_{3}][C_{6}H_{6}]$

But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.

Rate law for synthesis of S03 is as follows :

rate = $k_{1}[H_{2}SO_{4}]^{2}$

Hence when we substitute equation 2 in equation one,

Rate comes out to be = $k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]$

6 0

3 years ago

Why is not used at nuclear plant as a soverce for electrical energy

nikitadnepr [17]

The biggest reason is radioactive wastes. Nuclear power generated radioactive wastes like Uranimum, plutonium and amercium that inhibits gene expression and causes cancer to the environment. Nuclear plants use to release these wastes into the oceans, and it causes fishes to exhibit gender change, 3 eyes, 2 tails etc. The impact on human shows signs of serious blood, liver and lung cancers.

There are currently no way to get rid of these wastes as they take hundred thousands of years to decompose.

Another reason is they cause a small amount of green gas emission. Releases CO2 to the sky. They exhibit radioactive gas emission as well (causes cancer) .

7 0

3 years ago

Will velocities ever be equal?

Leni [432]

Velocities can be equal

6 0

3 years ago

Radiation refers to energetic waves and particles emitted by a radioactive source. Which of the following electromagnetic waves

ladessa [460]

Answer: Radio waves has the lowest energy and longest wavelength.

6 0

3 years ago

At its critical point, ammonia has a density of 0.235 g cm23. You have a special thickwalled glass tube that has a 10.0mm outs

salantis [7]

Answer:

$\large \boxed{\text{69.3 mg}}$

Explanation:

1. Volume of sealed tube

Assume the sealed tube is a right circular cylinder in which the cap and the base are also 4.20 mm thick.

Its outside dimensions are 155 mm long × 10.0 mm diameter.

Its inside dimensions are

h = 155 mm - 2 × 4.20 mm = 146.6 mm

r = 5.0 mm - 4.20 mm = 0.8 mm

V = πr²h = π(0.8)²× 146.6 mm³ = 294.8 mm³ = 0.2948 cm³

2. Calculate the mass of NH₃

$\begin{array}{rcl}\text{Density} & = & \dfrac{\text{Mass}}{\text{Volume}}\\\\\rho & = &\dfrac{m}{V}\\\\0.235 \text{ g$\cdot$ cm}^{-3} & = & \dfrac{m}{\text{0.2948 cm}^{3}}\\\\m & = & \text{0.0693 g}\\& = & \textbf{69.3 mg}\\\end{array}\\\text{You must seal $\large \boxed{\textbf{69.3 mg}}$ of ammonia in the tube.}$

4 0

3 years ago