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maksim [4K]
2 years ago
9

3. The complex ion Co(H2O)6 2(aq) is pink when placed in solution. Addition of chloride ions creates an equilibrium with CoCl42-

in the solution, which is blue in color. Write the balanced equation for the equilibrium. If CoCl42- solubility is endothermic, predict what will happen to the solution color if the solution is heated. What will happen if the solution is cooled
Chemistry
1 answer:
mart [117]2 years ago
6 0

Answer:

See explanation

Explanation:

When the complex ion Co(H2O)6 2+(aq) is placed in solution and chloride ions are added, the following equilobrium is set up;

  Co(H2O)62+(aq) + 4 Cl-(aq) <=> CoCl42-(aq) + 6 H2O(g)

Co(H2O)6 2+(aq) solution  is pink in colour while CoCl42-(aq) solution is blue in colour.

Since the solubility of CoCl42-(aq) is endothermic, heating the solution will move the equilibrium position towards the right (more CoCl42-(aq) is formed and the solution is blue in colour).

When the solution is cooled, more Co(H2O)62+(aq) is formed and the equilibrium position shifts towards the left and the solution becomes pink in colour.

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kp= 3.1 x 10^(-2)

Explanation:

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                                2SO2      +        O2         ⇄              2SO3

Initial                      3.4 atm           1.3 atm                         0 atm

Change                    -2x                    - x                                + 2x

Equilibrium            3.4 - 2x            1.3 -x                          0.52 atm

In order to know the x value:

2x = 0.52

x=(0.52)/2= 0.26

                               2SO2             +          O2              ⇄              2SO3

Equilibrium        3.4 - 0.52                1.3 - 0.26                     0.52 atm

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with the partial pressure in the equilibrium, we can obtain Kp.

Kp=\frac{PSO3^2}{PSO2^2 PO2}=\frac{(0.52)^2}{(2.88)^2(1.04)}=0.03135

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