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Hunter-Best [27]
3 years ago
5

How many liters of oxygen are necessary for the combustion of 425 g of sulfur, assuming that the reaction occurs at STP

Chemistry
1 answer:
WARRIOR [948]3 years ago
7 0

Answer:

V = 296.6 liters of oxygen.

Explanation:

The reaction of combustion of sulfur is:

O₂(g) + S(s) → SO₂(g)        (1)

To find the volume of the oxygen we need to use the Ideal Gas Law:

V = \frac{n_{O}RT}{P}   (2)

Where:

V: is the volume

n_{O}: is the number of moles of oxygen

R: is the gas constant = 0.082 L*atm/(K*mol)

T: is the temperature = 273 K (at STP)

P: is the pressure = 1 atm (at STP)

So we need to find the number of moles of oxygen that reacts with sulfur:

n_{S} = \frac{m}{M}

Where:

n_{S}: is the number of moles of sulfur

m: is the mass of sulfur = 425 g

M: is the molar mass of sulfur = 32.065 g/mol                                                                            

n_{S}=\frac{m}{M} =\frac{425 g}{32.065 g/mol} = 13.25 moles

From reaction (1) we have that 1 mol of O₂ reacts with 1 mol of S, hence the number of moles of oxygen is:

n_{S} = n_{O} = 13.25 moles  

Finally, the volume of oxygen is (equation (2)):

V = \frac{13.25 moles*0.082 L*atm/(K*mol)*273 K}{1 atm} = 296.6 L

Therefore, are necessary 296.6 liters of oxygen for the combustion of sulfur.

             

I hope it helps you!

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Answer:

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Consider the titration of 100.0 mL of 0.280 M propanoic acid (Ka = 1.3 ✕ 10−5) with 0.140 M NaOH. Calculate the pH of the result
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Answer:

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(b) 4.44

(c) 4.886

(d) 5.363

(e) 5.570

(f)  12.30

Explanation:

Here we have the titration of a weak acid with the strong base NaOH. So in part (a) simply calculate the pH of a weak acid ; in the other parts we have to consider that a buffer solution will be present after some of the weak acid reacts completely the strong base producing the conjugate base. We may even arrive to the situation in which all of the acid will be just consumed and have only  the weak base present in the solution treating it as the pOH and the pH = 14 -pOH. There is also the possibility that all of the weak base will be consumed and then the NaOH will drive the pH.

Lets call HA propanoic acid and A⁻ its conjugate base,

(a) pH = -log √ (HA) Ka =-log √(0.28 x 1.3 x 10⁻⁵) = 2.7

(b) moles reacted HA = 50 x 10⁻³ L x 0.14 mol/L = 0.007 mol

mol left HA = 0.28 - 0.007 = 0.021

mol A⁻ produced = 0.007

Using the Hasselbalch-Henderson equation for buffer solutions:

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Now we only a weak base present and its pH is given by:

pH  = √(kb x (A⁻)  where Kb= Kw/Ka

Notice that here we will have to calculate the concentration of A⁻ because we have dilution effects the moment we added to the 100 mL of HA,  200 mL of NaOH 0.14 M. (we did not need to concern ourselves before with this since the volumes cancelled each other in the previous formulas)

mol A⁻ = 0.028 mOl

Vol solution = 100 mL + 200 mL = 300 mL

(A⁻) = 0.028 mol /0.3 L = 0.0093 M

and we also need to calculate the Kb for the weak base:

Kw = 10⁻¹⁴ = ka Kb ⇒   Kb = 10⁻¹⁴/1.3x 10⁻⁵ = 7.7 x 10⁻ ¹⁰

pH = -log (√( 7.7 x 10⁻ ¹⁰ x 0.0093) = 5.570

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= 0.007 mol

(OH⁻) = 0.007 mol / 0.350 L = 2.00 x 10 ⁻²

pOH = - log (2.00 x 10⁻²) = 1.70

pH = 14 - 1.70 = 12.30

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