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Harlamova29_29 [7]
3 years ago
5

A beaker contains a 25 mL solution of an unknown monoprotic acid that reacts in a 1:1 stochiometric ratio with NaOH. Titrate the

solution with NaOH to determine the concentration of the acid.
Perform a titration by setting the concentration of the NaOH solution and adding it to the acid solution using the different.
Chemistry
1 answer:
Luden [163]3 years ago
8 0

Answer:

concentration of HCL = 4.56 g/dm3

Explanation:

If the titrant and analyte have a 1:1 mole ratio, the formula is molarity (M) of the acid x volume (V) of the acid = molarity (M) of the base x volume (V) of the base. (Molarity is the concentration of a solution expressed as the number of moles of solute per litre of solution.)

Step 1: Calculate the amount of sodium hydroxide in moles

Volume of sodium hydroxide solution = 25.0 ÷ 1,000 = 0.0250 dm3

Rearrange:

Concentration in mol/dm3 = \frac{\textup{amount~of~solute~in~mol}}{\textup{volume~in~dm}^3}

Amount of solutein mol = concentration in mol/dm3 × volume in dm3

Amount of sodium hydroxide = 0.100 × 0.0250

= 0.00250 mol

Step 2: Find the amount of hydrochloric acid in moles

The balanced equation is: NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)

So the mole ratio NaOH:HCl is 1:1

Therefore 0.00250 mol of NaOH reacts with 0.00250 mol of HCl

Step 3: Calculate the concentration of hydrochloric acid in mol/dm3

Volume of hydrochloric acid = 20.00 ÷ 1000 = 0.0200 dm3

Concentration in mol/dm3 = \frac{\textup{amount~of~solute~in~mol}}{\textup{volume~in~dm}^3}

Concentration in mol/dm3 = \frac{\textup{0.00250}}{\textup{0.0200}}

= 0.125 mol/dm3

Step 4: Calculate the concentration of hydrochloric acid in g/dm3

Relative formula mass of HCl = 1 + 35.5 = 36.5

Mass = relative formula mass × amount

Mass of HCl = 36.5 × 0.125

= 4.56 g

So concentration = 4.56 g/dm3

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4 0
3 years ago
Determine the [OH−] of a solution that is 0.115 M in CO32−. For carbonic acid (H2CO3), Ka1=4.3×10−7 and Ka2=5.6×10−11.
lianna [129]

Answer:

[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.

Explanation:

Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.

Analysis:

            H₂CO₃(aq)     ⇄     H⁺(aq)    +    HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷

C(i)          0.115M                      0                  0

ΔC              -x                        +x                  +x

C(eq)    0.115M - x                   x                    x

            ≅ 0.115M

Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M

= 4.3 x 10⁻⁷  => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.

In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion  concentration, the hydroxide ion concentration is then calculated from

[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.

________________________________________________________

NOTE: The 2.32 x 10⁻⁴M  value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.

4 0
3 years ago
How do you get hyphen notations?
laiz [17]

Answer:

In hyphen notation, the mass number is written after the name of the element. For example, in isotopic notation, the isotope of carbon that has a mass number of twelve would be represented as 12C . In hyphen notation, it would be written as carbon-12.

Explanation:

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3 years ago
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Reil [10]

Answer:

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8 0
2 years ago
Please help me with this question
Inessa05 [86]

From the calculation, the concentration in parts per billion is 6 ppb.

<h3>What is ppb?</h3>

The term ppb refers to the concentration of a substance in parts per billion. We obtain the ppb using the formula;

Mass of solute/ Mass of solution * 10^9

Now, 1L = 1000cm^3 = 1000 g

The concertation in ppb = 6 * 10^-6 g/1000 g * 10^9

= 6 ppb

Learn more about parts per billion:brainly.com/question/9179966

#SPJ1

4 0
2 years ago
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