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kumpel [21]
3 years ago
12

Reaction of ethylmagnesium bromide with which of the following compounds yields a primary alcohol after quenching with aqueous a

cid?
a. ethyl acetate
b. CH3CHO
c. (CH3)2CO
d. ethylene oxide
e. n- butyllithium
Chemistry
1 answer:
umka2103 [35]3 years ago
6 0

Answer

Option D

When a grignard Reagent reacts with Ethylene Oxide... A Primary Alcohol is Formed.

CH2OCH2 + RMgX ==> RCH2CH2OMgX

When You Hydrolyze

You have

RCH2CH2OH

The Text written below may come in handy someday.

Hope you find it helpful.

One of the preparation of Alcohols is via Reaction with "Grignard Reagents" .

Grignard Reagents have the formula "RMgX"

Where R is an alkyl group eg CH₃, C₂H₅ etc

X is a halogen eg Cl,Br etc

Ethylmagnesiumbromide fits the description of grignard Reagent from what I wrote above.

The formula for Ethylmagnesiumbromide is

"C₂H₅MgBr"

Now

When grignard reagents react with Alkanals... They form alcohols.

Note this trend.

When a grignard reagent reacts with Methanal(Formaldehyde)... It forms a Primary Alcohol.

When a grignard reagent reacts with any other Alkanal besides Methanal(formaldehyde) ... it forms Secondary Alcohols.

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29. What is E for a system which has the following two steps:
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Answer:

Zero

Explanation:

Recall that;

E = q + w

Where;

q = heat, w = work done

When heat is absorbed by the system q is positive

When heat is evolved by the system q is negative

When the system does work, w is negative

When work is done on the system w is positive

Step 1

ΔE1= 60 KJ + 40 KJ = 100KJ

Step 2

ΔE2= (-30 KJ) + (-70 KJ) = (-100) KJ

ΔE1 + ΔE2= 100KJ + (-100) KJ = 0KJ

4 0
3 years ago
When the following oxidation–reduction reaction in acidic solution is balanced, what is the lowest whole-number coefficient for
Svet_ta [14]

Answer:

c. 8, product side

Explanation:

In order to balance a redox reaction we use the ion-electron method, which has the following steps:

Step 1: identify oxidation and reduction half-reaction.

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Reduction: Br⁻(aq) → Br₂(l)

Step 2: perform the mass balance adding H⁺ and H₂O where necessary

8 H⁺(aq) + MnO₄⁻(aq) → Mn²⁺(aq) + 4 H₂O(l)

2 Br⁻(aq) → Br₂(l)

Step 3: perform the electrical balance adding electrons where necessary.

8 H⁺(aq) + MnO₄⁻(aq) + 5 e⁻ → Mn²⁺(aq) + 4 H₂O(l)

2 Br⁻(aq) → Br₂(l) + 2 e⁻

Step 4: multiply both half-reactions by numbers that secure that the number of electrons gained and lost are the same.

2 × (8 H⁺(aq) + MnO₄⁻(aq) + 5 e⁻ → Mn²⁺(aq) + 4 H₂O(l))

5 × (2 Br⁻(aq) → Br₂(l) + 2 e⁻)

Step 5: add both half-reactions side to side.

16 H⁺(aq) + 2 MnO₄⁻(aq) + 10 e⁻ + 10 Br⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 Br₂(l) + 10 e⁻

16 H⁺(aq) + 2 MnO₄⁻(aq) + 10 Br⁻(aq) → 2 Mn²⁺(aq) + 8 H₂O(l) + 5 Br₂(l)

3 0
3 years ago
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Firdavs [7]

Answer:

d. is the hydrostatic pressure produced on the surface of a semi-permeable membrane by osmosis.    

Explanation:

Osmosis -

It is the flow of the molecules of solvent from a region of higher concentration towards the region of lower concentration via a semipermeable membrane , is known as osmosis.

Osmotic pressure -

It refers to the minimum amount of pressure , which is required to be applied to the solution in order to avoid the flow of pure solvent via the semipermeable membrane , is referred to as osmotic pressure.

Or in simple terms ,

Osmotic pressure is the pressure applied to resists the process of osmosis.

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