The decomposition time : 7.69 min ≈ 7.7 min
<h3>Further explanation</h3>
Given
rate constant : 0.029/min
a concentration of 0.050 mol L to a concentration of 0.040 mol L
Required
the decomposition time
Solution
The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time
For first-order reaction :
[A]=[Ao]e^(-kt)
or
ln[A]=-kt+ln(A0)
Input the value :
ln(0.040)=-(0.029)t+ln(0.050)
-3.219 = -0.029t -2.996
-0.223 =-0.029t
t=7.69 minutes
The answer is a strike-slip. More specifically a right-lateral strike-slip.
<u>Ans: Acetic acid = 90.3 mM and Sodium acetate = 160 mM</u>
Given:
Acetic Acid/Sodium Acetate buffer of pH = 5.0
Let HA = acetic acid
A- = sodium acetate
Total concentration [HA] + [A-] = 250 mM ------(1)
pKa(acetic acid) = 4.75
Based on Henderson-Hasselbalch equation
pH = pKa + log[A-]/[HA]
[A-]/[HA] = 10^(pH-pKa) = 10^(5-4.75) = 10^0.25 = 1.77
[A-] = 1.77[HA] -----(2)
From (1) and (2)
[HA] + 1.77[HA] = 250 mM
[HA] = 250/2.77 = 90.25 mM
[A-] = 1.77(90.25) = 159.74 mM
Y : CCP : 4 atoms
X : tetrahedral voids would be 1/3 × 8 = 8/3
so formula would be Y12X8 or Y3X2 !!
