Answer:
The activation energy is 7.11 × 10⁴ J/mol.
Explanation:
Let's consider the Arrhenius equation.
where,
k is the rate constant
A is a collision factor
Ea is the activation energy
R is the ideal gas constant
T is the absolute temperature
The plot of ln k vs 1/T is a straight line with lnA as intercept and -Ea/R as slope. Then,
Explanation:
The given data is as follows.
= 286 kJ =
= 286000 J
,
Hence, formula to calculate entropy change of the reaction is as follows.
=
=
= 163.5 J/K
Therefore, formula to calculate electric work energy required is as follows.
=
= 237.277 kJ
Thus, we can conclude that the electrical work required for given situation is 237.277 kJ.
Here we have to draw the four isomers of the compound 3-bromo-4-fluorohexane.
The four isomers of the compound is shown in the figure.
In an organic molecule the chiral -C center is that where four (4) different groups are present. In 3-bromo-4-fluorohexane the 3 and 4 positions are chiral centers. The possible isomers of a molecule can be obtained from the formula 2n. As here 2 chiral centers are present thus number of stereoisomers will be 2×2 = 4.
The four different isomers as shown in the figure are 3R-, 4R-; 3S-, 4S; 3R, 4S and 3S-, 4R- 3-bromo-4-fluorohexane.
In the 3-bromo-4-fluorohexane the functional groups are -Br, C₂H₅, -C₃H₆F and -H for 3-position and -F, -C₂H₅, -C₃H₆ and -H for 4-position respectively.
The priority of the -3 position will be Br > C₃H₆F > C₂H₅ > H and for -4 position F > C₃H₆Br > C₂H₅ > H. If the rotation from the higher priority group to lower is clockwise and anticlockwise then the S- and R- notation are used respectively. However if the -H atom is present at the horizontal position then the notation will be reverse.
Thus the four isomers of the compound is shown.
