The toxic gar expelled from the reaction between gasoline and oxygen in the vehicle's engine is both Carbon dioxide and monoxide
To solve the problem, we assume the sample to be ideal. Then, we use the ideal gas equation which is expressed as PV = nRT. From the first condition of the nitrogen gas sample, we calculate the number of moles.
n = PV / RT
n = (98.7x 10^3 Pa x 0.01 m^3) / (8.314 Pa m^3/ mol K) x 298.15 K
n = 0.40 mol N2
At the second condition, the number of moles stays the same however pressure and temperature was changed. So, the new volume is calculated as follows:
V = nRT / P
V = 0.40 x 8.314 x 293.15 / 102.7 x 10^3
V = 9.49 x 10^-3 m^3 or 9.49 L
This is an application of Boyle's law:
P₁V₁ = P₂V₂. we don't have to convert volume and pressure to standard forms. we can even use the pressure with mmHg
1 atm = 760 mmHg
V₂ = P₁V₁ / P₂ = 745 x 500 / 760 = 490 ml
Note that here we assume constant temperature