Answer:
C.
will precipitate out first
the percentage of
remaining = 12.86%
Explanation:
Given that:
A solution contains:
![[Ca^{2+}] = 0.0440 \ M](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D%200.0440%20%5C%20M)
![[Ag^+] = 0.0940 \ M](https://tex.z-dn.net/?f=%5BAg%5E%2B%5D%20%3D%200.0940%20%5C%20M)
From the list of options , Let find the dissociation of 

where;
Solubility product constant Ksp of
is 
Thus;
![Ksp = [Ag^+]^3[PO_4^{3-}]](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BAg%5E%2B%5D%5E3%5BPO_4%5E%7B3-%7D%5D)
replacing the known values in order to determine the unknown ; we have :
![8.89 \times 10 ^{-17} = (0.0940)^3[PO_4^{3-}]](https://tex.z-dn.net/?f=8.89%20%5Ctimes%2010%20%5E%7B-17%7D%20%20%3D%20%280.0940%29%5E3%5BPO_4%5E%7B3-%7D%5D)
![\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3} = [PO_4^{3-}]](https://tex.z-dn.net/?f=%5Cdfrac%7B8.89%20%5Ctimes%2010%20%5E%7B-17%7D%7D%7B%280.0940%29%5E3%7D%20%20%3D%20%5BPO_4%5E%7B3-%7D%5D)
![[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D%5Cdfrac%7B8.89%20%5Ctimes%2010%20%5E%7B-17%7D%7D%7B%280.0940%29%5E3%7D)
![[PO_4^{3-}] =1.07 \times 10^{-13}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D1.07%20%5Ctimes%2010%5E%7B-13%7D)
The dissociation of 
The solubility product constant of
is 
The dissociation of
is :

Thus;
![Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![2.07 \times 10^{-33} = (0.0440)^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=2.07%20%5Ctimes%2010%5E%7B-33%7D%20%3D%20%280.0440%29%5E3%20%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}= [PO_4^{3-}]^2](https://tex.z-dn.net/?f=%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%280.0440%29%5E3%7D%3D%20%20%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%5E2%20%3D%20%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%280.0440%29%5E3%7D)
![[PO_4^{3-}]^2 = 2.43 \times 10^{-29}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%5E2%20%3D%202.43%20%5Ctimes%2010%5E%7B-29%7D)
![[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D%20%5Csqrt%7B2.43%20%5Ctimes%2010%5E%7B-29%7D)
![[PO_4^{3-}] =4.93 \times 10^{-15}](https://tex.z-dn.net/?f=%5BPO_4%5E%7B3-%7D%5D%20%3D4.93%20%5Ctimes%2010%5E%7B-15%7D)
Thus; the phosphate anion needed for precipitation is smaller i.e
in
than in

Therefore:
will precipitate out first
To determine the concentration of
when the second cation starts to precipitate ; we have :
![Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2](https://tex.z-dn.net/?f=Ksp%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%5BPO_4%5E%7B3-%7D%5D%5E2)
![2.07 \times 10^{-33} = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2](https://tex.z-dn.net/?f=2.07%20%5Ctimes%2010%5E%7B-33%7D%20%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5E3%20%281.07%20%5Ctimes%2010%5E%7B-13%7D%29%5E2)
![[Ca^{2+}]^3 = \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%5E3%20%3D%20%20%5Cdfrac%7B2.07%20%5Ctimes%2010%5E%7B-33%7D%20%7D%7B%281.07%20%5Ctimes%2010%5E%7B-13%7D%29%5E2%7D)
![[Ca^{2+}]^3 =1.808 \times 10^{-7}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%5E3%20%3D1.808%20%5Ctimes%2010%5E%7B-7%7D)
![[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D%5Csqrt%5B3%5D%7B1.808%20%5Ctimes%2010%5E%7B-7%7D%7D)
![[Ca^{2+}] =0.00566](https://tex.z-dn.net/?f=%5BCa%5E%7B2%2B%7D%5D%20%3D0.00566)
This implies that when the second cation starts to precipitate ; the concentration of
in the solution is 0.00566
Therefore;
the percentage of
remaining = concentration remaining/initial concentration × 100%
the percentage of
remaining = 0.00566/0.0440 × 100%
the percentage of
remaining = 0.1286 × 100%
the percentage of
remaining = 12.86%
Answer:
Like most other metals, Gallium is solid at room temperature (or liquid if it is too hot in your room). But, if it is held [in hands] for long enough, it melts in your hands, and doesn't poison you like Mercury would. This is because of its unusually low melting point of (~29 degree Centigrade).
- It melts once it reaches its melting point.
:)
<span>These values also increase from the
bottom to the top of a group because the size of the atom decreases, resulting
in a smaller distance between the nucleus and the valence electron shell, which
increases the attraction between the protons and electrons.</span>
Answer:
Kp = 0.049
Explanation:
The equilibrium in question is;
2 SO₂ (g) + O₂ (g) ⇄ 2 SO₃ (g)
Kp = p SO₃² / ( p SO₂² x p O₂ )
The initial pressures are given, so lets set up the ICE table for the equilibrium:
atm SO₂ O₂ SO₃
I 3.3 0.79 0
C -2x -x 2x
E 3.3 - 2x 0.79 - x 2x
We are told 2x = partial pressure of SO₃ is 0.47 atm at equilibrium, so we can determine the partial pressures of SO₂ and O₂ as follows:
p SO₂ = 3.3 -0.47 atm = 2.83 atm
p O₂ = 0.79 - (0.47/2) atm = .56 atm
Now we can calculate Kp:
Kp = 0.47² /[ ( 2.83 )² x 0.56 ] = 0.049 ( rounded to 2 significant figures )
Note that we have extra data in this problem we did not need since once we setup the ICE table for the equilibrium we realize we have all the information needed to solve the question.