Answer:
Explanation:
From the net ionic equation
Ba2+(aq) + SO42-(aq) ==> BaSO4(s) we see that 1 mole Ba2+ reacts with 1 mole SO42- to -> 1 mol BaSO4
Find moles of Ba2+ used: 0.250 moles/L x 0.0323 L = 0.008075 moles Ba2+
Find moles SO42- present: 0.008075 moles Ba2+ x 1 mol SO42-/1 mol Ba2+ = 0.008075 mol SO42-
Find mass of Na2SO4 present: 0.008075 mol SO42- x 1 mol Na2SO4/1 mol SO42- x 142.04 Na2SO4/mole = 1.14698 g = 1.15 g Na2SO4 (to 3 significant figures)
There will be chemical reaction(equation4Na+02--2Na20
Answer : The correct answer is 1) AlCl₃ - CH₃Cl 2) HNO₃ -H₂SO₄ at room temperature 3) Fuming HNO₃ -H₂SO₄ at 90-100 ⁰ C heat .
I think this reaction is forming 2,4,6- trinitrotoluene from benzene, since the product is not mentioned. Following are the steps to convert Benzene to 2,4,6 trinitrotoluene .
Step 1: Conversion of Benzene to Toluene .
Benzene can be converted to toluene by Friedel Craft Alkylation of benzene . In this reaction reagent AlCl₃ and Ch3Cl is used . Electrophile CH³⁺ is produced which attached on carbon of benzene and formation of Toluene and HCl occur.

Step 2 : Conversion of Toluene to dinitrotoluene.
Dinitritoluene is prepared from toluene by Nitration . This reaction uses Electrophilic substitution mechanism . The reagents used are HNO₃ and H₂SO₄ at room temperature . These reagents produces NO₂⁺ ( nitronium ion ), a electrophile which attacks on C2 and C4 Carbon atoms of Toluene.
Toluene 
Step 3) Conversion of Dinitro toluene to trinitrotoluene.
This reaction is extended nitration of toluene . Further nitration is done in extreme condition . The temperature of reaction is increased to 90- 100 ⁰ C . Due to which there is more production of NO²⁺ ion occurs from HNO₃ -H₂SO₄ and they attack on C6 carbon atom of dinitrotoluene which forms 2,4,6- trinitrotoluene.
Dinitrotoluene 
So over all reaction uses three reagents in order :

Answer: 4 : 3
Explanation:Please see attachment for explanation