The correct option is (b)
NaNH2 is an effective base. It can be a good nucleophile in the few situations where its strong basicity does not have negative side effects. It is employed in elimination reactions as well as the deprotonation of weak acids.Alkynes, alcohols, and a variety of other functional groups with acidic protons, such as esters and ketones, will all be deprotonated by NaNH2, a powerful base.Alkynes are deprotonated with NaNH2 to produce what are known as "acetylide" ions. These ions are powerful nucleophiles that can react with alkyl halides to create carbon-carbon bonds and add to carbonyls in an addition reaction.Acid/base and nucleophilic substitution are the two types of reactions.Using the right base, terminal alkynes can be deprotonated to produce a carbanion.A good C is the acetylide carbanion.The acetylide carbanion can undergo nucleophilic substitution reactions because it is a potent C nucleophile. (often SN2) with 1 or 2 alkyl halides with electrophilic C to create an internal alkyne (Cl, Br, or I).Elimination is more likely to occur with 3-alkyl halides.It is possible to swap either one or both of the terminal H atoms in ethylene (acetylene) to create monosubstituted (R-C-C-H) and symmetrical (R = R') or unsymmetrical (R not equal to R') disubstituted alkynes (R-C-C-R').
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Greater than 23mcg/dl is considered a high level of morning cortisol.
Normally, cortisol levels rise during the early morning hours and are highest about 7AM. They drop very low in the evening and during the early phase of sleep. If you do not have this daily change (diurnal rhythm) in cortisol levels, you may have overactive adrenal glands. This condition is called Cushing's syndrome.
