Electrophilic addition of bromine, Br2, to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermedia
te known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH2Cl2. In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism.
1 answer:
Answer:
See explanation and image attached for details
Explanation:
The reaction involves the heterolytic fission of the Br-Br bond in the bromine molecule to yield a bromine cation which attacks the but-1-ene to form a cyclic intermediate called the brominium ion. The bromine anion must now attack from the opposite face of the brominium ion due to steric clashes to form a product of a 1,2-dibromoalkane having the anti- stereochemistry.
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Answer:
See explanation
Explanation:
When we talk about electrophilic substitution, we are talking about a substitution reaction in which the attacking agent is an electrophile. The electrophile attacks an electron rich area of a compound during the reaction.
The five membered furan ring is aromatic just as benzene. This aromatic structure is maintained during electrophilic substitution reaction. The attack of the electrophile generates a resonance stabilized intermediate whose canonical structures have been shown in the image attached.
