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Aleksandr-060686 [28]
3 years ago
5

Electrophilic addition of bromine, Br2, to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermedia

te known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH2Cl2. In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism.

Chemistry
1 answer:
Taya2010 [7]3 years ago
5 0

Answer:

See explanation and image attached for details

Explanation:

The reaction involves the heterolytic fission of the Br-Br bond in the bromine molecule to yield a bromine cation which attacks the but-1-ene to form a cyclic intermediate called the brominium ion. The bromine anion must now attack from the opposite face of the brominium ion due to steric clashes to form a product of a 1,2-dibromoalkane having the anti- stereochemistry.

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Answer:

Here's what I get  

Explanation:

1. Balanced equation

HQ⁻ + CH₃-Br ⟶ HQ-CH₃ + Br⁻

(I must use HQ because the Brainly Editor thinks the O makes a forbidden word)

2. Mechanism

HQ⁻ + CH₃-Br ⟶[HQ···CH₃···Br]⁻⟶ HQ-CH₃ + Br⁻

        A                           C                         B

The hydroxide ion attacks the back side of the carbon atom in the bromomethane (A).

At the same time as the Q-H bond starts to form, the C-Br bond starts to break.

At the half-way point, we have a high-energy intermediate (C) with partially formed C-O and C-Br bonds.

As the reaction proceeds further, the Br atom drops off to form the products — methanol and bromide ion (B).

3. Energy diagram

See the diagram below.

 

8 0
3 years ago
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Explanation:

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In this question, Mass = 1000g, Volume = ? and Density = 100 Kg/L

For the units to be uniform, we convert 1000g to Kg = 1Kg

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6 0
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Answer:

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