Explanation:
Given -
- An organic compound gives H₂ gas with Na
- On treatment with alkaline iodine it gives yellow ppt.
- On oxidation with CrO₃/H⁺ forms an aldehyde (C₂H₄O)
To Find -
- Name the compound and write the reaction involved
Now,
Let A be the organic compound.
Then,
- A + Na → + H₂↑
- A + I₂ → CHI₃ (yellow ppt.)
- A + CrO₃ + H⁺ → C₂H₄O
Now,
Here we see that compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives aldehyde.
- Functional group of aldehyde = —CHO
And It forms only 2 Carbon aldehyde it means, It is Ethanal (CH₃CHO).
Compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives ethanal.
It means,
We know that 1° alcohol on oxidation gives aldehyde.
Here it gives 2 Carbon aldehyde.
It means,
Here 2 Carbon and 1° alcohol is used.
Now,
Its cleared that Compound A is Ethanol.
Reaction Involved -
- CH₃CH₂OH + Na → CH₃CH₂O⁻Na⁺ + H₂↑
- CH₃CH₂OH + I₂ + OH⁻ → CHI₃↓ + HCOO⁻ + HI + H₂O
- CH₃CH₂OH + CrO₃ + H⁺ → CH₃CHO
Explanation:
The given data is as follows.
T =
= (120 + 273.15)K = 393.15 K,
As it is given that it is an equimolar mixture of n-pentane and isopentane.
So,
= 0.5 and
= 0.5
According to the Antoine data, vapor pressure of two components at 393.15 K is as follows.
(393.15 K) = 9.2 bar
(393.15 K) = 10.5 bar
Hence, we will calculate the partial pressure of each component as follows.

= 
= 4.6 bar
and, 
= 
= 5.25 bar
Therefore, the bubble pressure will be as follows.
P =
= 4.6 bar + 5.25 bar
= 9.85 bar
Now, we will calculate the vapor composition as follows.

= 
= 0.467
and, 
= 
= 0.527
Calculate the dew point as follows.
= 0.5,
= 0.5


= 0.101966
P = 9.807
Composition of the liquid phase is
and its formula is as follows.

= 
= 0.5329

= 
= 0.467
Answer:
b is ur answer the temputer does increase
Explanation: