To convert a mass of a substance to units of moles, we would need the molar mass of the substance since is it describes the mass of one mole of that substance. For CuCl2, the molar mass is 134.45 g/mol. For Al, the atomic mass is 26.98 g/mol.
2.50 g CuCl2 ( 1 mol / 134.45) = 0.019 mol CuCl2
0.25 g Al ( 1 mol / 26.98 g ) = 0.0093 mol Al
The reaction;
O(g) +O2(g)→O3(g), ΔH = sum of bond enthalpy of reactants-sum of food enthalpy of products.
ΔH = ( bond enthalpy of O(g)+bond enthalpy of O2 (g) - bond enthalpy of O3(g)
-107.2 kJ/mol = O+487.7kJ/mol =O+487.7 kJ/mol +487.7kJ/mol =594.9 kJ/mol
Bond enthalpy (BE) of O3(g) is equals to 2× bond enthalpy of O3(g) because, O3(g) has two types of bonds from its lewis structure (0-0=0).
∴2BE of O3(g) = 594.9kJ/mol
Average bond enthalpy = 594.9kJ/mol/2
=297.45kJ/mol
∴ Averange bond enthalpy of O3(g) is 297.45kJ/mol.
When ketone is reacted with phosphorous pentachloride, chlorination takes place at the carbonyl carbon with substitution of the oxygen atom to give a geminal dichloride (with 2 Cl atoms on same carbon) according to the following equation:
so we can say that acetone is converted into 2,2-dichloropropane by action of PCl₅
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