To calculate the <span>δ h, we must balance first the reaction:
NO + 0.5O2 -----> NO2
Then we write all the reactions,
2O3 -----> 3O2 </span><span>δ h = -426 kj eq. (1)
O2 -----> 2O </span><span>δ h = 490 kj eq. (2)
NO + O3 -----> NO2 + O2 </span><span>δ h = -200 kj eq. (3)
We divide eq. (1) by 2, we get
</span>O3 -----> 1.5O2 δ h = -213 kj eq. (4)
Then, we subtract eq. (3) by eq. (4)
NO + O3 -----> NO2 + O2 δ h = -200 kj
- (O3 -----> 1.5 O2 δ h = -213 kj)
NO -----> NO2 - 0.5O2 δ h = 13 kj eq. (5)
eq. (2) divided by -2. (Note: Dividing or multiplying by negative number reverses the reaction)
O -----> 0.5O2 <span>δ h = -245 kj eq. (6)
</span>
Add eq. (6) to eq. (5), we get
NO -----> NO2 - 0.5O2 δ h = 13 kj
+ O -----> 0.5O2 δ h = -245 kj
NO + O ----> NO2 δ h = -232 kj
<em>ANSWER:</em> <em>NO + O ----> NO2 δ h = -232 kj</em>
Answer:
See explanation below
Explanation:
The question is incomplete, cause you are not providing the structure. However, I found the question and it's attached in picture 1.
Now, according to this reaction and the product given, we can see that we have sustitution reaction. In the absence of sodium methoxide, the reaction it's no longer in basic medium, so the sustitution reaction that it's promoted here it's not an Sn2 reaction as part a), but instead a Sn1 reaction, and in this we can have the presence of carbocation. What happen here then?, well, the bromine leaves the molecule leaving a secondary carbocation there, but the neighbour carbon (The one in the cycle) has a more stable carbocation, so one atom of hydrogen from that carbon migrates to the carbon with the carbocation to stabilize that carbon, and the result is a tertiary carbocation. When this happens, the methanol can easily go there and form the product.
For question 6a, as it was stated before, the mechanism in that reaction is a Sn2, however, we can have conditions for an E2 reaction and form an alkene. This can be done, cause the extoxide can substract the atoms of hydrogens from either the carbon of the cycle or the terminal methyl of the molecule and will form two different products of elimination. The product formed in greater quantities will be the one where the negative charge is more stable, in this case, in the primary carbon of the methyl it's more stable there, so product 1 will be formed more (See picture 2)
For question 6b, same principle of 6a, when the hydrogen migrates to the 2nd carbocation to form a tertiary carbocation the methanol will promove an E1 reaction with the vecinal carbons and form two eliminations products. See picture 2 for mechanism of reaction.
Rivers, oceans, lakes, ponds
Is this a real question? It’s B
Answer:
it’s mass was greater than when it started
Explanation:
When a metal is coated with another metal, the plating metal deposits on the plated metal. Usually, the plating metal functions as the anode while the plated metal functions on the cathode. The anode metal is oxidized and reduced at the cathode and become deposited on the cathode material. This increases the mass of the cathode. Hence the mass of the silver/gold product is greater than the mass of silver at the beginning of the electroplating process.