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blondinia [14]
3 years ago
9

Methanol, ethanol, and n-propanol are three common alcohols. When 1.00 g of n-propanol (C3H7OH)is burned in air, -33.4 kJ of hea

t is liberated. Calculate the heat of combustion of n-propanol in kJ/mol.
Chemistry
1 answer:
Inga [223]3 years ago
5 0

Answer : The heat of combustion of n-propanol is 0.554 kJ/mol

Explanation :

First we have to calculate the moles of n-propanol.

\text{Moles of n-propanol}=\frac{\text{Mass of n-propanol}}{\text{Molar mass of n-propanol}}

Molar mass of n-propanol = 60.09 g/mole

\text{Moles of n-propanol}=\frac{1.00g}{60.09g/mole}=0.0166mole

Now we have to calculate the heat of combustion of n-propanol.

As, 0.0166 mole of n-propanol liberated heat of combustion = -33.4 kJ

So, 1 mole of n-propanol liberated heat of combustion = 0.0166 × (-33.4 kJ)

                                                                                           = 0.554 kJ/mol

Therefore, the heat of combustion of n-propanol is 0.554 kJ/mol

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Answer:

2HC₆H₁₁NHSO₃ + BaCO₃ → Ba(C₆H₁₁NHSO₃)₂ + H₂CO₃;

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2HC₆H₁₁NHSO₃ + Ca(OH)₂ → Ca(C₆H₁₁NHSO₃)₂ + 2H₂O

Explanation:

First, let's see the reactants for the first reaction and how they dissociate:

HC₆H₁₁NHSO₃ → H⁺ + C₆H₁₁NHSO₃⁻

BaCO₃ → Ba²⁺ + CO₃²⁻ (Barium is from group 2, so its cation has charge +2)

So, to form the products, the cation of one will join the anion of others. The amount of the cation will be the charge of the anion, and the amount of the anion will be the charge of the cation:

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The reaction then is:

HC₆H₁₁NHSO₃ + BaCO₃ → Ba(C₆H₁₁NHSO₃)₂ + H₂CO₃

The number of elements must be the same on both sides, so the balanced equation is

2HC₆H₁₁NHSO₃ + BaCO₃ → Ba(C₆H₁₁NHSO₃)₂ + H₂CO₃

The treatment with H₂SO₄ will produce:

H₂SO₄ → 2H⁺ + SO₄⁻²

Ba(C₆H₁₁NHSO₃)₂ → Ba²⁺ + C₆H₁₁NHSO₃⁻

The balanced reaction will be then:

Ba(C₆H₁₁NHSO₃)₂ + H₂SO₄ → BaSO₄ + 2HC₆H₁₁NHSO₃

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HC₆H₁₁NHSO₃ → H⁺ + C₆H₁₁NHSO₃⁻

Ca(OH)₂ → Ca²⁺ + 2OH⁻

The balance reaction will be:

2HC₆H₁₁NHSO₃ + Ca(OH)₂ → Ca(C₆H₁₁NHSO₃)₂ + 2H₂O

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